Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects

Synthesized Fe0-rGO nanocomposite with ratio of 1/1 (w/w) was prepared and has been used as adsorbent for the removal of Carbamazepine (CBZ) from aqueous solution. The adsorbent was characterized by various techniques such as Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray sp...

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Autores principales:	Leila Zamani, Sodeh Sadjadi, Fatemeh Ashouri, Mahsa Jahangiri-rad
Formato:	article
Lenguaje:	EN
Publicado:	IWA Publishing 2021
Materias:	adsorption carbamazepine nano zerovalent iron optimization reduced graphene oxide Environmental technology. Sanitary engineering TD1-1066
Acceso en línea:	https://doaj.org/article/f92ca2756f654ec3bda14ec2a4eb95d3
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spelling	oai:doaj.org-article:f92ca2756f654ec3bda14ec2a4eb95d32021-11-23T18:41:07ZCarbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects0273-12231996-973210.2166/wst.2021.457https://doaj.org/article/f92ca2756f654ec3bda14ec2a4eb95d32021-11-01T00:00:00Zhttp://wst.iwaponline.com/content/84/9/2557https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732Synthesized Fe0-rGO nanocomposite with ratio of 1/1 (w/w) was prepared and has been used as adsorbent for the removal of Carbamazepine (CBZ) from aqueous solution. The adsorbent was characterized by various techniques such as Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and Field Emission Scanning Electron Microscopy (FE-SEM) analyses. Linear experiments were performed to compare the best fitting isotherms and kinetics. The Freundlich isotherm (R2>0.90) and pseudo second order kinetic (R2>0.99) fitted well the experimental data. On the basis of the Langmuir isotherm, the maximum adsorption capacity of Fe0-rGO for CBZ was up to 50 mg g−1 at 30 °C. The pH, adsorbent dose, and initial concentration of CBZ were observed to be the leading parameters that affected the removal of CBZ considering the analysis of variance (ANOVA; p<0.05). The optimum process value of variables obtained by numerical optimization corresponds to pH 3.07, an adsorbent dose of 36.2 mg, an initial CBZ concentration of 5 mg L–1 and at 30.15 °C. The results of optimum conditions reveal that a maximum of 94% removal efficiency can be achieved; whereas, this phenomenon was independent of temperature (p-value>0.05). Moreover, Fe0-rGO can be used to remove diclofenac (DIC) and cetirizine (CTZ) simultaneously. To sum up, the Fe0-rGO is a promising adsorbent not only for the efficient removal of CBZ but also for the reduction of coexisting drugs in aqueous solution. HIGHLIGHTS The nanocomposite was successfully synthesized.; The adsorption of three hard to remove drugs was investigated.; The effect of various parameters on CBZ removal were determined.; The optimum condition for CBZ removal was obtained.; The interference of coexisting drugs on CBZ adsorption was investigated.;Leila ZamaniSodeh SadjadiFatemeh AshouriMahsa Jahangiri-radIWA Publishingarticleadsorptioncarbamazepinenano zerovalent ironoptimizationreduced graphene oxideEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 84, Iss 9, Pp 2557-2577 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	adsorption carbamazepine nano zerovalent iron optimization reduced graphene oxide Environmental technology. Sanitary engineering TD1-1066
spellingShingle	adsorption carbamazepine nano zerovalent iron optimization reduced graphene oxide Environmental technology. Sanitary engineering TD1-1066 Leila Zamani Sodeh Sadjadi Fatemeh Ashouri Mahsa Jahangiri-rad Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
description	Synthesized Fe0-rGO nanocomposite with ratio of 1/1 (w/w) was prepared and has been used as adsorbent for the removal of Carbamazepine (CBZ) from aqueous solution. The adsorbent was characterized by various techniques such as Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and Field Emission Scanning Electron Microscopy (FE-SEM) analyses. Linear experiments were performed to compare the best fitting isotherms and kinetics. The Freundlich isotherm (R2>0.90) and pseudo second order kinetic (R2>0.99) fitted well the experimental data. On the basis of the Langmuir isotherm, the maximum adsorption capacity of Fe0-rGO for CBZ was up to 50 mg g−1 at 30 °C. The pH, adsorbent dose, and initial concentration of CBZ were observed to be the leading parameters that affected the removal of CBZ considering the analysis of variance (ANOVA; p<0.05). The optimum process value of variables obtained by numerical optimization corresponds to pH 3.07, an adsorbent dose of 36.2 mg, an initial CBZ concentration of 5 mg L–1 and at 30.15 °C. The results of optimum conditions reveal that a maximum of 94% removal efficiency can be achieved; whereas, this phenomenon was independent of temperature (p-value>0.05). Moreover, Fe0-rGO can be used to remove diclofenac (DIC) and cetirizine (CTZ) simultaneously. To sum up, the Fe0-rGO is a promising adsorbent not only for the efficient removal of CBZ but also for the reduction of coexisting drugs in aqueous solution. HIGHLIGHTS The nanocomposite was successfully synthesized.; The adsorption of three hard to remove drugs was investigated.; The effect of various parameters on CBZ removal were determined.; The optimum condition for CBZ removal was obtained.; The interference of coexisting drugs on CBZ adsorption was investigated.;
format	article
author	Leila Zamani Sodeh Sadjadi Fatemeh Ashouri Mahsa Jahangiri-rad
author_facet	Leila Zamani Sodeh Sadjadi Fatemeh Ashouri Mahsa Jahangiri-rad
author_sort	Leila Zamani
title	Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
title_short	Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
title_full	Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
title_fullStr	Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
title_full_unstemmed	Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects
title_sort	carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (fe0-rgo) composite: theory, process optimization, and coexisting drugs effects
publisher	IWA Publishing
publishDate	2021
url	https://doaj.org/article/f92ca2756f654ec3bda14ec2a4eb95d3
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Carbamazepine removal from aqueous solution by synthesized reduced graphene oxide-nano zero valent iron (Fe0-rGO) composite: theory, process optimization, and coexisting drugs effects

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