Direct observation of mode-specific phonon-band gap coupling in methylammonium lead halide perovskites

Methylammonium lead iodide perovskite, a promising material for efficient photovoltaics, shows a unique temperature dependence of its optical properties. Kim et al. quantify the coupling between the optical gap and a lattice phonon at 1 THz, which favorably contributes to the thermal variation of th...

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Auteurs principaux: Heejae Kim, Johannes Hunger, Enrique Cánovas, Melike Karakus, Zoltán Mics, Maksim Grechko, Dmitry Turchinovich, Sapun H. Parekh, Mischa Bonn
Format: article
Langue:EN
Publié: Nature Portfolio 2017
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Accès en ligne:https://doaj.org/article/f964e7c1d0934ab3ba9a9484ddbb77f8
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Résumé:Methylammonium lead iodide perovskite, a promising material for efficient photovoltaics, shows a unique temperature dependence of its optical properties. Kim et al. quantify the coupling between the optical gap and a lattice phonon at 1 THz, which favorably contributes to the thermal variation of the gap.