NO3− anions can act as Lewis acid in the solid state
The nitrate anion, NO3−, is typically thought of as an electron-donating molecular moiety. Here the authors reveal, however, that when the negative charge on NO3−is smeared out over a large enough area, a positive potential emerges on N that can act as a Lewis acid in the solid state.
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2017
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oai:doaj.org-article:f9ca2a1e800c46e38a0751bcd7d4ecbc2021-12-02T17:06:11ZNO3− anions can act as Lewis acid in the solid state10.1038/ncomms145222041-1723https://doaj.org/article/f9ca2a1e800c46e38a0751bcd7d4ecbc2017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14522https://doaj.org/toc/2041-1723The nitrate anion, NO3−, is typically thought of as an electron-donating molecular moiety. Here the authors reveal, however, that when the negative charge on NO3−is smeared out over a large enough area, a positive potential emerges on N that can act as a Lewis acid in the solid state.Antonio BauzáAntonio FronteraTiddo J. MooibroekNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017) |
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Science Q Antonio Bauzá Antonio Frontera Tiddo J. Mooibroek NO3− anions can act as Lewis acid in the solid state |
| description |
The nitrate anion, NO3−, is typically thought of as an electron-donating molecular moiety. Here the authors reveal, however, that when the negative charge on NO3−is smeared out over a large enough area, a positive potential emerges on N that can act as a Lewis acid in the solid state. |
| format |
article |
| author |
Antonio Bauzá Antonio Frontera Tiddo J. Mooibroek |
| author_facet |
Antonio Bauzá Antonio Frontera Tiddo J. Mooibroek |
| author_sort |
Antonio Bauzá |
| title |
NO3− anions can act as Lewis acid in the solid state |
| title_short |
NO3− anions can act as Lewis acid in the solid state |
| title_full |
NO3− anions can act as Lewis acid in the solid state |
| title_fullStr |
NO3− anions can act as Lewis acid in the solid state |
| title_full_unstemmed |
NO3− anions can act as Lewis acid in the solid state |
| title_sort |
no3− anions can act as lewis acid in the solid state |
| publisher |
Nature Portfolio |
| publishDate |
2017 |
| url |
https://doaj.org/article/f9ca2a1e800c46e38a0751bcd7d4ecbc |
| work_keys_str_mv |
AT antoniobauza no3anionscanactaslewisacidinthesolidstate AT antoniofrontera no3anionscanactaslewisacidinthesolidstate AT tiddojmooibroek no3anionscanactaslewisacidinthesolidstate |
| _version_ |
1718381709543604224 |