Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure

Sorption properties of various biochars have been extensively investigated by many researchers. One of the parameters that have a significant impact on sorption properties is pyrolysis temperature. This paper presents a study on the effect of pyrolysis temperature (425, 575, 725 °C) on the sorption...

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Autores principales: Jolanta Sobik-Szołtysek, Katarzyna Wystalska, Krystyna Malińska, Erik Meers
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:fa4fb5700cf442fa92341c39fe75d39d2021-11-11T18:07:18ZInfluence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure10.3390/ma142165661996-1944https://doaj.org/article/fa4fb5700cf442fa92341c39fe75d39d2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6566https://doaj.org/toc/1996-1944Sorption properties of various biochars have been extensively investigated by many researchers. One of the parameters that have a significant impact on sorption properties is pyrolysis temperature. This paper presents a study on the effect of pyrolysis temperature (425, 575, 725 °C) on the sorption properties of poultry-manure-derived biochar (BPM). The produced biochars, i.e., BPM425, BPM575 and BPM725, demonstrated specific properties at 425, 525 and 752 °C such as high pH (10.40, 10.65 and 12.45), high ash contents (52.07, 61.74 and 78.38%) and relatively low BET (Brunauer, Emmett and Teller) surface area (11, 17 and 19 m<sup>2</sup>·g<sup>−1</sup>). The analysis of the mineral phases of the BPMs confirmed the buffering capacity. The investigated biochars were tested for sorption of Zn, Cd and Pb in mono-, double- and triple-metal batch sorption tests. According to the obtained results, biochar produced at a temperature of 575 °C (BPM575) can function as a sufficient sorbent for the removal of Zn, Cd and Pb from a water solution. The presented results do not confirm the effect of competing metal ions on the sorption efficiency of the selected metals by the investigated biochars. Based on that, the studied biochar sorbents can be used in environments contaminated with many metals.Jolanta Sobik-SzołtysekKatarzyna WystalskaKrystyna MalińskaErik MeersMDPI AGarticlepoultry manurebiocharpyrolysis temperaturesorptionheavy metalssoil contaminationTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6566, p 6566 (2021)
institution DOAJ
collection DOAJ
language EN
topic poultry manure
biochar
pyrolysis temperature
sorption
heavy metals
soil contamination
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle poultry manure
biochar
pyrolysis temperature
sorption
heavy metals
soil contamination
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Jolanta Sobik-Szołtysek
Katarzyna Wystalska
Krystyna Malińska
Erik Meers
Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
description Sorption properties of various biochars have been extensively investigated by many researchers. One of the parameters that have a significant impact on sorption properties is pyrolysis temperature. This paper presents a study on the effect of pyrolysis temperature (425, 575, 725 °C) on the sorption properties of poultry-manure-derived biochar (BPM). The produced biochars, i.e., BPM425, BPM575 and BPM725, demonstrated specific properties at 425, 525 and 752 °C such as high pH (10.40, 10.65 and 12.45), high ash contents (52.07, 61.74 and 78.38%) and relatively low BET (Brunauer, Emmett and Teller) surface area (11, 17 and 19 m<sup>2</sup>·g<sup>−1</sup>). The analysis of the mineral phases of the BPMs confirmed the buffering capacity. The investigated biochars were tested for sorption of Zn, Cd and Pb in mono-, double- and triple-metal batch sorption tests. According to the obtained results, biochar produced at a temperature of 575 °C (BPM575) can function as a sufficient sorbent for the removal of Zn, Cd and Pb from a water solution. The presented results do not confirm the effect of competing metal ions on the sorption efficiency of the selected metals by the investigated biochars. Based on that, the studied biochar sorbents can be used in environments contaminated with many metals.
format article
author Jolanta Sobik-Szołtysek
Katarzyna Wystalska
Krystyna Malińska
Erik Meers
author_facet Jolanta Sobik-Szołtysek
Katarzyna Wystalska
Krystyna Malińska
Erik Meers
author_sort Jolanta Sobik-Szołtysek
title Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
title_short Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
title_full Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
title_fullStr Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
title_full_unstemmed Influence of Pyrolysis Temperature on the Heavy Metal Sorption Capacity of Biochar from Poultry Manure
title_sort influence of pyrolysis temperature on the heavy metal sorption capacity of biochar from poultry manure
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/fa4fb5700cf442fa92341c39fe75d39d
work_keys_str_mv AT jolantasobikszołtysek influenceofpyrolysistemperatureontheheavymetalsorptioncapacityofbiocharfrompoultrymanure
AT katarzynawystalska influenceofpyrolysistemperatureontheheavymetalsorptioncapacityofbiocharfrompoultrymanure
AT krystynamalinska influenceofpyrolysistemperatureontheheavymetalsorptioncapacityofbiocharfrompoultrymanure
AT erikmeers influenceofpyrolysistemperatureontheheavymetalsorptioncapacityofbiocharfrompoultrymanure
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