A selenium-catalysed para-amination of phenols

Selenium has emerged as a metalloid for the catalytic construction of C–N bonds; however no functionalisation of aromatic compounds has been developed yet. Here, the authors report the para-amination of phenols via two successive sigmatropic rearrangements of a redox versatile Se–N bond.

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Autores principales:	Dingyuan Yan, Guoqiang Wang, Feng Xiong, Wei-Yin Sun, Zhuangzhi Shi, Yi Lu, Shuhua Li, Jing Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/fa771ff099694b4dad78032b777422b7
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spelling	oai:doaj.org-article:fa771ff099694b4dad78032b777422b72021-12-02T15:34:49ZA selenium-catalysed para-amination of phenols10.1038/s41467-018-06763-42041-1723https://doaj.org/article/fa771ff099694b4dad78032b777422b72018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06763-4https://doaj.org/toc/2041-1723Selenium has emerged as a metalloid for the catalytic construction of C–N bonds; however no functionalisation of aromatic compounds has been developed yet. Here, the authors report the para-amination of phenols via two successive sigmatropic rearrangements of a redox versatile Se–N bond.Dingyuan YanGuoqiang WangFeng XiongWei-Yin SunZhuangzhi ShiYi LuShuhua LiJing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dingyuan Yan Guoqiang Wang Feng Xiong Wei-Yin Sun Zhuangzhi Shi Yi Lu Shuhua Li Jing Zhao A selenium-catalysed para-amination of phenols
description	Selenium has emerged as a metalloid for the catalytic construction of C–N bonds; however no functionalisation of aromatic compounds has been developed yet. Here, the authors report the para-amination of phenols via two successive sigmatropic rearrangements of a redox versatile Se–N bond.
format	article
author	Dingyuan Yan Guoqiang Wang Feng Xiong Wei-Yin Sun Zhuangzhi Shi Yi Lu Shuhua Li Jing Zhao
author_facet	Dingyuan Yan Guoqiang Wang Feng Xiong Wei-Yin Sun Zhuangzhi Shi Yi Lu Shuhua Li Jing Zhao
author_sort	Dingyuan Yan
title	A selenium-catalysed para-amination of phenols
title_short	A selenium-catalysed para-amination of phenols
title_full	A selenium-catalysed para-amination of phenols
title_fullStr	A selenium-catalysed para-amination of phenols
title_full_unstemmed	A selenium-catalysed para-amination of phenols
title_sort	selenium-catalysed para-amination of phenols
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/fa771ff099694b4dad78032b777422b7
work_keys_str_mv	AT dingyuanyan aseleniumcatalysedparaaminationofphenols AT guoqiangwang aseleniumcatalysedparaaminationofphenols AT fengxiong aseleniumcatalysedparaaminationofphenols AT weiyinsun aseleniumcatalysedparaaminationofphenols AT zhuangzhishi aseleniumcatalysedparaaminationofphenols AT yilu aseleniumcatalysedparaaminationofphenols AT shuhuali aseleniumcatalysedparaaminationofphenols AT jingzhao aseleniumcatalysedparaaminationofphenols AT dingyuanyan seleniumcatalysedparaaminationofphenols AT guoqiangwang seleniumcatalysedparaaminationofphenols AT fengxiong seleniumcatalysedparaaminationofphenols AT weiyinsun seleniumcatalysedparaaminationofphenols AT zhuangzhishi seleniumcatalysedparaaminationofphenols AT yilu seleniumcatalysedparaaminationofphenols AT shuhuali seleniumcatalysedparaaminationofphenols AT jingzhao seleniumcatalysedparaaminationofphenols
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A selenium-catalysed para-amination of phenols

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