A selenium-catalysed para-amination of phenols

Selenium has emerged as a metalloid for the catalytic construction of C–N bonds; however no functionalisation of aromatic compounds has been developed yet. Here, the authors report the para-amination of phenols via two successive sigmatropic rearrangements of a redox versatile Se–N bond.

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Auteurs principaux: Dingyuan Yan, Guoqiang Wang, Feng Xiong, Wei-Yin Sun, Zhuangzhi Shi, Yi Lu, Shuhua Li, Jing Zhao
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/fa771ff099694b4dad78032b777422b7
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