Arene dearomatization through a catalytic N-centered radical cascade reaction

Arene dearomatization reactions allow chemists to rapidly build unique chemical architectures from largely available starting materials. Here, the authors show a photocatalytic carboamination/dearomatization cascade process leading to 1,4-cyclohexadiene-fused sultams via N-centered radicals.

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Autores principales: Rory C. McAtee, Efrey A. Noten, Corey R. J. Stephenson
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/fab209fa1c37460da0791187c95c689d
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spelling oai:doaj.org-article:fab209fa1c37460da0791187c95c689d2021-12-02T16:51:08ZArene dearomatization through a catalytic N-centered radical cascade reaction10.1038/s41467-020-16369-42041-1723https://doaj.org/article/fab209fa1c37460da0791187c95c689d2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16369-4https://doaj.org/toc/2041-1723Arene dearomatization reactions allow chemists to rapidly build unique chemical architectures from largely available starting materials. Here, the authors show a photocatalytic carboamination/dearomatization cascade process leading to 1,4-cyclohexadiene-fused sultams via N-centered radicals.Rory C. McAteeEfrey A. NotenCorey R. J. StephensonNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Rory C. McAtee
Efrey A. Noten
Corey R. J. Stephenson
Arene dearomatization through a catalytic N-centered radical cascade reaction
description Arene dearomatization reactions allow chemists to rapidly build unique chemical architectures from largely available starting materials. Here, the authors show a photocatalytic carboamination/dearomatization cascade process leading to 1,4-cyclohexadiene-fused sultams via N-centered radicals.
format article
author Rory C. McAtee
Efrey A. Noten
Corey R. J. Stephenson
author_facet Rory C. McAtee
Efrey A. Noten
Corey R. J. Stephenson
author_sort Rory C. McAtee
title Arene dearomatization through a catalytic N-centered radical cascade reaction
title_short Arene dearomatization through a catalytic N-centered radical cascade reaction
title_full Arene dearomatization through a catalytic N-centered radical cascade reaction
title_fullStr Arene dearomatization through a catalytic N-centered radical cascade reaction
title_full_unstemmed Arene dearomatization through a catalytic N-centered radical cascade reaction
title_sort arene dearomatization through a catalytic n-centered radical cascade reaction
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/fab209fa1c37460da0791187c95c689d
work_keys_str_mv AT rorycmcatee arenedearomatizationthroughacatalyticncenteredradicalcascadereaction
AT efreyanoten arenedearomatizationthroughacatalyticncenteredradicalcascadereaction
AT coreyrjstephenson arenedearomatizationthroughacatalyticncenteredradicalcascadereaction
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