Influence of synthesis parameters on crystallization behavior and ionic conductivity of the Li4PS4I solid electrolyte

Abstract Superionic solid electrolytes are key to the development of advanced solid-state Li batteries. In recent years, various materials have been discovered, with ionic conductivities approaching or even exceeding those of carbonate-based liquid electrolytes used in high-performance Li-ion batter...

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Autores principales: Florian Strauss, Jing Lin, Jürgen Janek, Torsten Brezesinski
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/fabcce2a06b947958ffa5b549aa34ba9
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Sumario:Abstract Superionic solid electrolytes are key to the development of advanced solid-state Li batteries. In recent years, various materials have been discovered, with ionic conductivities approaching or even exceeding those of carbonate-based liquid electrolytes used in high-performance Li-ion batteries. Among the different classes of inorganic solid electrolytes under study, lithium thiophosphates are one of the most promising due to their high Li-ion conductivity at room temperature and mechanical softness. Here, we report about the effect of synthesis parameters on the crystallization behavior and charge-transport properties of Li4PS4I. We show that thermally induced crystallization of Li4PS4I (P4/nmm), starting from the glassy phase 1.5Li2S–0.5P2S5–LiI, adversely affects the material’s conductivity. However, both conductivity and crystallization temperature can be significantly increased by applying pressure during the preparation.