A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption
As the largest and most representative tributary of the Mekong River, the Mun River Basin (MRB) provides critical understanding of regional hydro-geochemical features and rock weathering processes on a basin scale. The present study measured strontium (Sr) isotopes with hydro-geochemistry data of 56...
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2021
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oai:doaj.org-article:fb384435f5df4d589af9326f35d2efb82021-11-11T19:58:25ZA Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption10.3390/w132131372073-4441https://doaj.org/article/fb384435f5df4d589af9326f35d2efb82021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4441/13/21/3137https://doaj.org/toc/2073-4441As the largest and most representative tributary of the Mekong River, the Mun River Basin (MRB) provides critical understanding of regional hydro-geochemical features and rock weathering processes on a basin scale. The present study measured strontium (Sr) isotopes with hydro-geochemistry data of 56 water samples in detail in the MRB in northeast Thailand. The dissolved Sr contents and <sup>87</sup>Sr/<sup>86</sup>Sr isotopic ratios were reported to be 8.7–344.6 μg/L (average 126.9 μg/L) and 0.7085–0.7281 (average 0.7156), respectively. The concentrations of dissolved Sr in the mainstream slightly decreased from upstream to downstream, while the variation trend of <sup>87</sup>Sr/<sup>86</sup>Sr was on the contrary. Correlation analysis showed that Na<sup>+</sup> strongly correlated with Cl<sup>−</sup> (0.995, <i>p</i> < 0.01), while Ca<sup>2+</sup> exhibited weak relationships with SO<sub>4</sub><sup>2</sup><sup>−</sup> (0.356, <i>p</i> < 0.01). Samples of the MRB exhibited lower Mg<sup>2+</sup>/Na<sup>+</sup>, Ca<sup>2+</sup>/Na<sup>+</sup>, HCO<sub>3</sub><sup>−</sup>/Na<sup>+</sup> and 1000Sr/Na ratios, and gathered around the end-member of evaporite dissolution, with slight shift to silicate weathering end-member, demonstrating the dominant contribution of evaporite dissolution and silicate weathering on dissolved loads. Comparing with data of major world rivers from previous research, our results remained consistency with rivers draining through similar geological conditions. The dissolved Sr flux to the adjacent Mekong River was estimated to be 20.7 tons/year. In accordance with the forward model, silicate weathering rate and CO<sub>2</sub> consumption rate during dry season were calculated to be 0.73 tons/km<sup>2</sup>/year and 1.94 × 10<sup>4</sup> mol/km<sup>2</sup>/year, and may get underestimated due to intense water consumption by extensive agricultural activities. The superimposed effect of anthropogenic impacts on the water environment could enhance chemical weathering, and thus should be taken into account in regional ion cycles and carbon budgets. These findings highlight the coupling analysis of Sr isotopes and hydro-geochemistry in Earth surface processes and provide basic investigation for sustainable regional water treatment mechanisms in the pan basin of the Mekong River.Shitong ZhangGuilin HanJie ZengXuhuan XiaoFairda MalemMDPI AGarticlestrontium isotopewater chemistrychemical weatheringMekong tributaryThailandCO<sub>2</sub> consumptionHydraulic engineeringTC1-978Water supply for domestic and industrial purposesTD201-500ENWater, Vol 13, Iss 3137, p 3137 (2021) |
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DOAJ |
| collection |
DOAJ |
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EN |
| topic |
strontium isotope water chemistry chemical weathering Mekong tributary Thailand CO<sub>2</sub> consumption Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500 |
| spellingShingle |
strontium isotope water chemistry chemical weathering Mekong tributary Thailand CO<sub>2</sub> consumption Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500 Shitong Zhang Guilin Han Jie Zeng Xuhuan Xiao Fairda Malem A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| description |
As the largest and most representative tributary of the Mekong River, the Mun River Basin (MRB) provides critical understanding of regional hydro-geochemical features and rock weathering processes on a basin scale. The present study measured strontium (Sr) isotopes with hydro-geochemistry data of 56 water samples in detail in the MRB in northeast Thailand. The dissolved Sr contents and <sup>87</sup>Sr/<sup>86</sup>Sr isotopic ratios were reported to be 8.7–344.6 μg/L (average 126.9 μg/L) and 0.7085–0.7281 (average 0.7156), respectively. The concentrations of dissolved Sr in the mainstream slightly decreased from upstream to downstream, while the variation trend of <sup>87</sup>Sr/<sup>86</sup>Sr was on the contrary. Correlation analysis showed that Na<sup>+</sup> strongly correlated with Cl<sup>−</sup> (0.995, <i>p</i> < 0.01), while Ca<sup>2+</sup> exhibited weak relationships with SO<sub>4</sub><sup>2</sup><sup>−</sup> (0.356, <i>p</i> < 0.01). Samples of the MRB exhibited lower Mg<sup>2+</sup>/Na<sup>+</sup>, Ca<sup>2+</sup>/Na<sup>+</sup>, HCO<sub>3</sub><sup>−</sup>/Na<sup>+</sup> and 1000Sr/Na ratios, and gathered around the end-member of evaporite dissolution, with slight shift to silicate weathering end-member, demonstrating the dominant contribution of evaporite dissolution and silicate weathering on dissolved loads. Comparing with data of major world rivers from previous research, our results remained consistency with rivers draining through similar geological conditions. The dissolved Sr flux to the adjacent Mekong River was estimated to be 20.7 tons/year. In accordance with the forward model, silicate weathering rate and CO<sub>2</sub> consumption rate during dry season were calculated to be 0.73 tons/km<sup>2</sup>/year and 1.94 × 10<sup>4</sup> mol/km<sup>2</sup>/year, and may get underestimated due to intense water consumption by extensive agricultural activities. The superimposed effect of anthropogenic impacts on the water environment could enhance chemical weathering, and thus should be taken into account in regional ion cycles and carbon budgets. These findings highlight the coupling analysis of Sr isotopes and hydro-geochemistry in Earth surface processes and provide basic investigation for sustainable regional water treatment mechanisms in the pan basin of the Mekong River. |
| format |
article |
| author |
Shitong Zhang Guilin Han Jie Zeng Xuhuan Xiao Fairda Malem |
| author_facet |
Shitong Zhang Guilin Han Jie Zeng Xuhuan Xiao Fairda Malem |
| author_sort |
Shitong Zhang |
| title |
A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| title_short |
A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| title_full |
A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| title_fullStr |
A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| title_full_unstemmed |
A Strontium and Hydro-Geochemical Perspective on Human Impacted Tributary of the Mekong River Basin: Sources Identification, Fluxes, and CO<sub>2</sub> Consumption |
| title_sort |
strontium and hydro-geochemical perspective on human impacted tributary of the mekong river basin: sources identification, fluxes, and co<sub>2</sub> consumption |
| publisher |
MDPI AG |
| publishDate |
2021 |
| url |
https://doaj.org/article/fb384435f5df4d589af9326f35d2efb8 |
| work_keys_str_mv |
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