Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides

Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides generating a diverse pool of valuable chiral...

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Autores principales:	Nuligonda Thirupathi, Fang Wei, Chen-Ho Tung, Zhenghu Xu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/fbd60ab92da64a6fa3568cb7784c4645
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spelling	oai:doaj.org-article:fbd60ab92da64a6fa3568cb7784c46452021-12-02T17:02:09ZDivergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides10.1038/s41467-019-11134-82041-1723https://doaj.org/article/fbd60ab92da64a6fa3568cb7784c46452019-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11134-8https://doaj.org/toc/2041-1723Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides generating a diverse pool of valuable chiral cyclic azides.Nuligonda ThirupathiFang WeiChen-Ho TungZhenghu XuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Nuligonda Thirupathi Fang Wei Chen-Ho Tung Zhenghu Xu Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
description	Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides generating a diverse pool of valuable chiral cyclic azides.
format	article
author	Nuligonda Thirupathi Fang Wei Chen-Ho Tung Zhenghu Xu
author_facet	Nuligonda Thirupathi Fang Wei Chen-Ho Tung Zhenghu Xu
author_sort	Nuligonda Thirupathi
title	Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
title_short	Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
title_full	Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
title_fullStr	Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
title_full_unstemmed	Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
title_sort	divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/fbd60ab92da64a6fa3568cb7784c4645
work_keys_str_mv	AT nuligondathirupathi divergentsynthesisofchiralcyclicazidesviaasymmetriccycloadditionreactionsofvinylazides AT fangwei divergentsynthesisofchiralcyclicazidesviaasymmetriccycloadditionreactionsofvinylazides AT chenhotung divergentsynthesisofchiralcyclicazidesviaasymmetriccycloadditionreactionsofvinylazides AT zhenghuxu divergentsynthesisofchiralcyclicazidesviaasymmetriccycloadditionreactionsofvinylazides
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Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides

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