Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus

Asymmetrically substituted phosphine ligands play a decisive role in catalysis, but their synthesis is rather challenging and often involves hazardous chemicals such as PCl3 or PH3. Here, the authors report the one-pot preparation of asymmetric phosphines from white phosphorus via a pentaphosphaferr...

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Autores principales:	Stephan Reichl, Eric Mädl, Felix Riedlberger, Martin Piesch, Gábor Balázs, Michael Seidl, Manfred Scheer
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/fc0054bb3c154684a05404a5a726a097
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spelling	oai:doaj.org-article:fc0054bb3c154684a05404a5a726a0972021-12-02T17:18:12ZPentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus10.1038/s41467-021-26002-72041-1723https://doaj.org/article/fc0054bb3c154684a05404a5a726a0972021-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26002-7https://doaj.org/toc/2041-1723Asymmetrically substituted phosphine ligands play a decisive role in catalysis, but their synthesis is rather challenging and often involves hazardous chemicals such as PCl3 or PH3. Here, the authors report the one-pot preparation of asymmetric phosphines from white phosphorus via a pentaphosphaferrocene based modular system, in which the transition metal complex can be reused.Stephan ReichlEric MädlFelix RiedlbergerMartin PieschGábor BalázsMichael SeidlManfred ScheerNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Stephan Reichl Eric Mädl Felix Riedlberger Martin Piesch Gábor Balázs Michael Seidl Manfred Scheer Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
description	Asymmetrically substituted phosphine ligands play a decisive role in catalysis, but their synthesis is rather challenging and often involves hazardous chemicals such as PCl3 or PH3. Here, the authors report the one-pot preparation of asymmetric phosphines from white phosphorus via a pentaphosphaferrocene based modular system, in which the transition metal complex can be reused.
format	article
author	Stephan Reichl Eric Mädl Felix Riedlberger Martin Piesch Gábor Balázs Michael Seidl Manfred Scheer
author_facet	Stephan Reichl Eric Mädl Felix Riedlberger Martin Piesch Gábor Balázs Michael Seidl Manfred Scheer
author_sort	Stephan Reichl
title	Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
title_short	Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
title_full	Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
title_fullStr	Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
title_full_unstemmed	Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
title_sort	pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/fc0054bb3c154684a05404a5a726a097
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Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus

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