Atomistic characterization of the active-site solvation dynamics of a model photocatalyst

Interactions between reactive excited states of molecular photocatalysts and surrounding solvent can dictate reaction pathways, but are not readily accessible to conventional spectroscopic methods. Here the authors use diffuse X-ray scattering and theory to study the atomistic solvation dynamics of...

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Autores principales:	Tim B. van Driel, Kasper S. Kjær, Robert W. Hartsock, Asmus O. Dohn, Tobias Harlang, Matthieu Chollet, Morten Christensen, Wojciech Gawelda, Niels E. Henriksen, Jong Goo Kim, Kristoffer Haldrup, Kyung Hwan Kim, Hyotcherl Ihee, Jeongho Kim, Henrik Lemke, Zheng Sun, Villy Sundström, Wenkai Zhang, Diling Zhu, Klaus B. Møller, Martin M. Nielsen, Kelly J. Gaffney
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/fc2761474a3545f8abc536d15c7246a2
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spelling	oai:doaj.org-article:fc2761474a3545f8abc536d15c7246a22021-12-02T16:50:13ZAtomistic characterization of the active-site solvation dynamics of a model photocatalyst10.1038/ncomms136782041-1723https://doaj.org/article/fc2761474a3545f8abc536d15c7246a22016-11-01T00:00:00Zhttps://doi.org/10.1038/ncomms13678https://doaj.org/toc/2041-1723Interactions between reactive excited states of molecular photocatalysts and surrounding solvent can dictate reaction pathways, but are not readily accessible to conventional spectroscopic methods. Here the authors use diffuse X-ray scattering and theory to study the atomistic solvation dynamics of a photoexcited di-iridium complex in acetonitrile.Tim B. van DrielKasper S. KjærRobert W. HartsockAsmus O. DohnTobias HarlangMatthieu CholletMorten ChristensenWojciech GaweldaNiels E. HenriksenJong Goo KimKristoffer HaldrupKyung Hwan KimHyotcherl IheeJeongho KimHenrik LemkeZheng SunVilly SundströmWenkai ZhangDiling ZhuKlaus B. MøllerMartin M. NielsenKelly J. GaffneyNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tim B. van Driel Kasper S. Kjær Robert W. Hartsock Asmus O. Dohn Tobias Harlang Matthieu Chollet Morten Christensen Wojciech Gawelda Niels E. Henriksen Jong Goo Kim Kristoffer Haldrup Kyung Hwan Kim Hyotcherl Ihee Jeongho Kim Henrik Lemke Zheng Sun Villy Sundström Wenkai Zhang Diling Zhu Klaus B. Møller Martin M. Nielsen Kelly J. Gaffney Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
description	Interactions between reactive excited states of molecular photocatalysts and surrounding solvent can dictate reaction pathways, but are not readily accessible to conventional spectroscopic methods. Here the authors use diffuse X-ray scattering and theory to study the atomistic solvation dynamics of a photoexcited di-iridium complex in acetonitrile.
format	article
author	Tim B. van Driel Kasper S. Kjær Robert W. Hartsock Asmus O. Dohn Tobias Harlang Matthieu Chollet Morten Christensen Wojciech Gawelda Niels E. Henriksen Jong Goo Kim Kristoffer Haldrup Kyung Hwan Kim Hyotcherl Ihee Jeongho Kim Henrik Lemke Zheng Sun Villy Sundström Wenkai Zhang Diling Zhu Klaus B. Møller Martin M. Nielsen Kelly J. Gaffney
author_facet	Tim B. van Driel Kasper S. Kjær Robert W. Hartsock Asmus O. Dohn Tobias Harlang Matthieu Chollet Morten Christensen Wojciech Gawelda Niels E. Henriksen Jong Goo Kim Kristoffer Haldrup Kyung Hwan Kim Hyotcherl Ihee Jeongho Kim Henrik Lemke Zheng Sun Villy Sundström Wenkai Zhang Diling Zhu Klaus B. Møller Martin M. Nielsen Kelly J. Gaffney
author_sort	Tim B. van Driel
title	Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
title_short	Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
title_full	Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
title_fullStr	Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
title_full_unstemmed	Atomistic characterization of the active-site solvation dynamics of a model photocatalyst
title_sort	atomistic characterization of the active-site solvation dynamics of a model photocatalyst
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/fc2761474a3545f8abc536d15c7246a2
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Atomistic characterization of the active-site solvation dynamics of a model photocatalyst

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