Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
Abstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed...
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2021
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oai:doaj.org-article:fc47aa2197e840668e9860afb7dd7a282021-11-08T11:19:15ZSynthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature10.1186/s13065-021-00784-92661-801Xhttps://doaj.org/article/fc47aa2197e840668e9860afb7dd7a282021-11-01T00:00:00Zhttps://doi.org/10.1186/s13065-021-00784-9https://doaj.org/toc/2661-801XAbstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. Graphical AbstractLi ZhuokeCao JunMao TingNi DanBMCarticleThiazoleBimannich baseCorrosion inhibitorHigh temperature resistanceChemistryQD1-999ENBMC Chemistry, Vol 15, Iss 1, Pp 1-8 (2021) |
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Thiazole Bimannich base Corrosion inhibitor High temperature resistance Chemistry QD1-999 |
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Thiazole Bimannich base Corrosion inhibitor High temperature resistance Chemistry QD1-999 Li Zhuoke Cao Jun Mao Ting Ni Dan Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
description |
Abstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. Graphical Abstract |
format |
article |
author |
Li Zhuoke Cao Jun Mao Ting Ni Dan |
author_facet |
Li Zhuoke Cao Jun Mao Ting Ni Dan |
author_sort |
Li Zhuoke |
title |
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
title_short |
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
title_full |
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
title_fullStr |
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
title_full_unstemmed |
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature |
title_sort |
synthesis of bimannich base with thiazole and its corrosion inhibition effect on h2s and co2 at high temperature |
publisher |
BMC |
publishDate |
2021 |
url |
https://doaj.org/article/fc47aa2197e840668e9860afb7dd7a28 |
work_keys_str_mv |
AT lizhuoke synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature AT caojun synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature AT maoting synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature AT nidan synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature |
_version_ |
1718442297261031424 |