Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature

Abstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed...

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Autores principales: Li Zhuoke, Cao Jun, Mao Ting, Ni Dan
Formato: article
Lenguaje:EN
Publicado: BMC 2021
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Acceso en línea:https://doaj.org/article/fc47aa2197e840668e9860afb7dd7a28
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spelling oai:doaj.org-article:fc47aa2197e840668e9860afb7dd7a282021-11-08T11:19:15ZSynthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature10.1186/s13065-021-00784-92661-801Xhttps://doaj.org/article/fc47aa2197e840668e9860afb7dd7a282021-11-01T00:00:00Zhttps://doi.org/10.1186/s13065-021-00784-9https://doaj.org/toc/2661-801XAbstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. Graphical AbstractLi ZhuokeCao JunMao TingNi DanBMCarticleThiazoleBimannich baseCorrosion inhibitorHigh temperature resistanceChemistryQD1-999ENBMC Chemistry, Vol 15, Iss 1, Pp 1-8 (2021)
institution DOAJ
collection DOAJ
language EN
topic Thiazole
Bimannich base
Corrosion inhibitor
High temperature resistance
Chemistry
QD1-999
spellingShingle Thiazole
Bimannich base
Corrosion inhibitor
High temperature resistance
Chemistry
QD1-999
Li Zhuoke
Cao Jun
Mao Ting
Ni Dan
Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
description Abstract A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. Graphical Abstract
format article
author Li Zhuoke
Cao Jun
Mao Ting
Ni Dan
author_facet Li Zhuoke
Cao Jun
Mao Ting
Ni Dan
author_sort Li Zhuoke
title Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
title_short Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
title_full Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
title_fullStr Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
title_full_unstemmed Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature
title_sort synthesis of bimannich base with thiazole and its corrosion inhibition effect on h2s and co2 at high temperature
publisher BMC
publishDate 2021
url https://doaj.org/article/fc47aa2197e840668e9860afb7dd7a28
work_keys_str_mv AT lizhuoke synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature
AT caojun synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature
AT maoting synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature
AT nidan synthesisofbimannichbasewiththiazoleanditscorrosioninhibitioneffectonh2sandco2athightemperature
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