Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet

Aluminum fumarate metal organic frameworks (AlFu MOFs) pellet was successfully prepared with outstanding porous structure and its CO2 adsorption performance was investigated. As the binder mass increased, the pellet mechanical strength rose while the CO2 adsorption capacity reduced. The chosen AlFu...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Lijiao Ma, Yudong Ding, Fengqi Zeng, Xingxing Zhao, Qiang Liao, Hong Wang, Xun Zhu
Formato:	article
Lenguaje:	EN
Publicado:	AIDIC Servizi S.r.l. 2021
Materias:	Chemical engineering TP155-156 Computer engineering. Computer hardware TK7885-7895
Acceso en línea:	https://doaj.org/article/fd3d27bf6bab4b16911c2b6c56f34e75
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:fd3d27bf6bab4b16911c2b6c56f34e75
record_format	dspace
spelling	oai:doaj.org-article:fd3d27bf6bab4b16911c2b6c56f34e752021-11-15T21:46:55ZPreparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet10.3303/CET21882102283-9216https://doaj.org/article/fd3d27bf6bab4b16911c2b6c56f34e752021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/12003https://doaj.org/toc/2283-9216Aluminum fumarate metal organic frameworks (AlFu MOFs) pellet was successfully prepared with outstanding porous structure and its CO2 adsorption performance was investigated. As the binder mass increased, the pellet mechanical strength rose while the CO2 adsorption capacity reduced. The chosen AlFu pellet with 2.5wt% carboxymethyl cellulose sodium (CMC) binder retained the micro-morphology characteristics with a specific surface area of 726.06 m2/g and micropore volume of 0.33 cm3/g. The adsorption performance of CO2 by the pellets was studied at different partial pressures and temperatures. The results showed that the adsorption capacity of CO2 in AlFu pellet was increased with lower adsorption temperature and higher CO2 partial pressure, the maximum adsorption amount was 1.26 mmol/g at 35 °C and 1.0 bar. The CO2 adsorption kinetics and the limiting factors for adsorption rate were analyzed. Compared with pseudo-second order model the pseudo-first order kinetic model can better describe the CO2 physical adsorption behavior of AlFu pellet. The rate-limiting kinetic analysis revealed that the CO2 adsorption rate was determined by film diffusion and intra-particle diffusion rather than inter-particle diffusion.Lijiao MaYudong DingFengqi ZengXingxing ZhaoQiang LiaoHong WangXun ZhuAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemical engineering TP155-156 Computer engineering. Computer hardware TK7885-7895
spellingShingle	Chemical engineering TP155-156 Computer engineering. Computer hardware TK7885-7895 Lijiao Ma Yudong Ding Fengqi Zeng Xingxing Zhao Qiang Liao Hong Wang Xun Zhu Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
description	Aluminum fumarate metal organic frameworks (AlFu MOFs) pellet was successfully prepared with outstanding porous structure and its CO2 adsorption performance was investigated. As the binder mass increased, the pellet mechanical strength rose while the CO2 adsorption capacity reduced. The chosen AlFu pellet with 2.5wt% carboxymethyl cellulose sodium (CMC) binder retained the micro-morphology characteristics with a specific surface area of 726.06 m2/g and micropore volume of 0.33 cm3/g. The adsorption performance of CO2 by the pellets was studied at different partial pressures and temperatures. The results showed that the adsorption capacity of CO2 in AlFu pellet was increased with lower adsorption temperature and higher CO2 partial pressure, the maximum adsorption amount was 1.26 mmol/g at 35 °C and 1.0 bar. The CO2 adsorption kinetics and the limiting factors for adsorption rate were analyzed. Compared with pseudo-second order model the pseudo-first order kinetic model can better describe the CO2 physical adsorption behavior of AlFu pellet. The rate-limiting kinetic analysis revealed that the CO2 adsorption rate was determined by film diffusion and intra-particle diffusion rather than inter-particle diffusion.
format	article
author	Lijiao Ma Yudong Ding Fengqi Zeng Xingxing Zhao Qiang Liao Hong Wang Xun Zhu
author_facet	Lijiao Ma Yudong Ding Fengqi Zeng Xingxing Zhao Qiang Liao Hong Wang Xun Zhu
author_sort	Lijiao Ma
title	Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
title_short	Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
title_full	Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
title_fullStr	Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
title_full_unstemmed	Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet
title_sort	preparation and co2 adsorption performance of porous aluminum fumarate mofs pellet
publisher	AIDIC Servizi S.r.l.
publishDate	2021
url	https://doaj.org/article/fd3d27bf6bab4b16911c2b6c56f34e75
work_keys_str_mv	AT lijiaoma preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT yudongding preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT fengqizeng preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT xingxingzhao preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT qiangliao preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT hongwang preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet AT xunzhu preparationandco2adsorptionperformanceofporousaluminumfumaratemofspellet
_version_	1718426883085828096

Preparation and CO2 Adsorption Performance of Porous Aluminum Fumarate MOFs Pellet

Ejemplares similares