Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction

Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Ana María Martínez-Gualda, Rafael Cano, Leyre Marzo, Raúl Pérez-Ruiz, Javier Luis-Barrera, Rubén Mas-Ballesté, Alberto Fraile, Víctor A. de la Peña O’Shea, José Alemán
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
Materias:
Q
Acceso en línea:https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db86
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
Descripción
Sumario:Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product.