Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated...
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Nature Portfolio
2019
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oai:doaj.org-article:fd3d2e4fba32438aa7e7ccec9808db862021-12-02T14:39:16ZChromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction10.1038/s41467-019-10441-42041-1723https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db862019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10441-4https://doaj.org/toc/2041-1723Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product.Ana María Martínez-GualdaRafael CanoLeyre MarzoRaúl Pérez-RuizJavier Luis-BarreraRubén Mas-BallestéAlberto FraileVíctor A. de la Peña O’SheaJosé AlemánNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Ana María Martínez-Gualda Rafael Cano Leyre Marzo Raúl Pérez-Ruiz Javier Luis-Barrera Rubén Mas-Ballesté Alberto Fraile Víctor A. de la Peña O’Shea José Alemán Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
description |
Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product. |
format |
article |
author |
Ana María Martínez-Gualda Rafael Cano Leyre Marzo Raúl Pérez-Ruiz Javier Luis-Barrera Rubén Mas-Ballesté Alberto Fraile Víctor A. de la Peña O’Shea José Alemán |
author_facet |
Ana María Martínez-Gualda Rafael Cano Leyre Marzo Raúl Pérez-Ruiz Javier Luis-Barrera Rubén Mas-Ballesté Alberto Fraile Víctor A. de la Peña O’Shea José Alemán |
author_sort |
Ana María Martínez-Gualda |
title |
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
title_short |
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
title_full |
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
title_fullStr |
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
title_full_unstemmed |
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction |
title_sort |
chromoselective access to z- or e- allylated amines and heterocycles by a photocatalytic allylation reaction |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db86 |
work_keys_str_mv |
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