Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction

Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated...

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Autores principales: Ana María Martínez-Gualda, Rafael Cano, Leyre Marzo, Raúl Pérez-Ruiz, Javier Luis-Barrera, Rubén Mas-Ballesté, Alberto Fraile, Víctor A. de la Peña O’Shea, José Alemán
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db86
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spelling oai:doaj.org-article:fd3d2e4fba32438aa7e7ccec9808db862021-12-02T14:39:16ZChromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction10.1038/s41467-019-10441-42041-1723https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db862019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10441-4https://doaj.org/toc/2041-1723Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product.Ana María Martínez-GualdaRafael CanoLeyre MarzoRaúl Pérez-RuizJavier Luis-BarreraRubén Mas-BallestéAlberto FraileVíctor A. de la Peña O’SheaJosé AlemánNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Ana María Martínez-Gualda
Rafael Cano
Leyre Marzo
Raúl Pérez-Ruiz
Javier Luis-Barrera
Rubén Mas-Ballesté
Alberto Fraile
Víctor A. de la Peña O’Shea
José Alemán
Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
description Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product.
format article
author Ana María Martínez-Gualda
Rafael Cano
Leyre Marzo
Raúl Pérez-Ruiz
Javier Luis-Barrera
Rubén Mas-Ballesté
Alberto Fraile
Víctor A. de la Peña O’Shea
José Alemán
author_facet Ana María Martínez-Gualda
Rafael Cano
Leyre Marzo
Raúl Pérez-Ruiz
Javier Luis-Barrera
Rubén Mas-Ballesté
Alberto Fraile
Víctor A. de la Peña O’Shea
José Alemán
author_sort Ana María Martínez-Gualda
title Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
title_short Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
title_full Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
title_fullStr Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
title_full_unstemmed Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction
title_sort chromoselective access to z- or e- allylated amines and heterocycles by a photocatalytic allylation reaction
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/fd3d2e4fba32438aa7e7ccec9808db86
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