CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbo...
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2021
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oai:doaj.org-article:fd5c5390b4c94b418d6a3ced8399f4aa2021-11-25T16:40:55ZCdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices10.3390/app1122109142076-3417https://doaj.org/article/fd5c5390b4c94b418d6a3ced8399f4aa2021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/22/10914https://doaj.org/toc/2076-3417Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbonacrite film over CdS via CBD, where the film acted as a precursor film to be converted to PbSe via ion exchange. The characterization of each material involved in the heterostructure were as follows: the CdS thin films presented a hexagonal crystalline structure and bandgap of 2.42 eV; PbSe had a cubic structure and a bandgap of 0.34 eV. I vs. V measurements allowed the observation of the electrical behavior, which showed a change from an ohmic to diode response by applying a thermal annealing at 150 °C for 5 min. The forward bias of the diode response was in the order of 0.8 V, and the current-voltage characteristics were analyzed by using the modified Shockley model, obtaining an ideality factor of 2.47, being similar to a Schottky diode. Therefore, the reported process to synthesize an ITO/CdS/PbSe heterostructure by aqueous chemical methods was successful and could be used to develop optoelectronic devices.José Antonio Heredia-CancinoOscar SalcidoRicardo Britto-HurtadoSayra Guadalupe Ruvalcaba-ManzoRamón Ochoa-LandínSantos Jesús CastilloMDPI AGarticleheterojunctioncadmium sulfidelead selenidechemical bath depositioncost-effective processesscalabilityTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10914, p 10914 (2021) |
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heterojunction cadmium sulfide lead selenide chemical bath deposition cost-effective processes scalability Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 |
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heterojunction cadmium sulfide lead selenide chemical bath deposition cost-effective processes scalability Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 José Antonio Heredia-Cancino Oscar Salcido Ricardo Britto-Hurtado Sayra Guadalupe Ruvalcaba-Manzo Ramón Ochoa-Landín Santos Jesús Castillo CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
description |
Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbonacrite film over CdS via CBD, where the film acted as a precursor film to be converted to PbSe via ion exchange. The characterization of each material involved in the heterostructure were as follows: the CdS thin films presented a hexagonal crystalline structure and bandgap of 2.42 eV; PbSe had a cubic structure and a bandgap of 0.34 eV. I vs. V measurements allowed the observation of the electrical behavior, which showed a change from an ohmic to diode response by applying a thermal annealing at 150 °C for 5 min. The forward bias of the diode response was in the order of 0.8 V, and the current-voltage characteristics were analyzed by using the modified Shockley model, obtaining an ideality factor of 2.47, being similar to a Schottky diode. Therefore, the reported process to synthesize an ITO/CdS/PbSe heterostructure by aqueous chemical methods was successful and could be used to develop optoelectronic devices. |
format |
article |
author |
José Antonio Heredia-Cancino Oscar Salcido Ricardo Britto-Hurtado Sayra Guadalupe Ruvalcaba-Manzo Ramón Ochoa-Landín Santos Jesús Castillo |
author_facet |
José Antonio Heredia-Cancino Oscar Salcido Ricardo Britto-Hurtado Sayra Guadalupe Ruvalcaba-Manzo Ramón Ochoa-Landín Santos Jesús Castillo |
author_sort |
José Antonio Heredia-Cancino |
title |
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
title_short |
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
title_full |
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
title_fullStr |
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
title_full_unstemmed |
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices |
title_sort |
cds/pbse heterojunction made via chemical bath deposition and ionic exchange processes to develop low-cost and scalable devices |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/fd5c5390b4c94b418d6a3ced8399f4aa |
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