CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices

Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbo...

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Autores principales: José Antonio Heredia-Cancino, Oscar Salcido, Ricardo Britto-Hurtado, Sayra Guadalupe Ruvalcaba-Manzo, Ramón Ochoa-Landín, Santos Jesús Castillo
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:fd5c5390b4c94b418d6a3ced8399f4aa2021-11-25T16:40:55ZCdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices10.3390/app1122109142076-3417https://doaj.org/article/fd5c5390b4c94b418d6a3ced8399f4aa2021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/22/10914https://doaj.org/toc/2076-3417Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbonacrite film over CdS via CBD, where the film acted as a precursor film to be converted to PbSe via ion exchange. The characterization of each material involved in the heterostructure were as follows: the CdS thin films presented a hexagonal crystalline structure and bandgap of 2.42 eV; PbSe had a cubic structure and a bandgap of 0.34 eV. I vs. V measurements allowed the observation of the electrical behavior, which showed a change from an ohmic to diode response by applying a thermal annealing at 150 °C for 5 min. The forward bias of the diode response was in the order of 0.8 V, and the current-voltage characteristics were analyzed by using the modified Shockley model, obtaining an ideality factor of 2.47, being similar to a Schottky diode. Therefore, the reported process to synthesize an ITO/CdS/PbSe heterostructure by aqueous chemical methods was successful and could be used to develop optoelectronic devices.José Antonio Heredia-CancinoOscar SalcidoRicardo Britto-HurtadoSayra Guadalupe Ruvalcaba-ManzoRamón Ochoa-LandínSantos Jesús CastilloMDPI AGarticleheterojunctioncadmium sulfidelead selenidechemical bath depositioncost-effective processesscalabilityTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10914, p 10914 (2021)
institution DOAJ
collection DOAJ
language EN
topic heterojunction
cadmium sulfide
lead selenide
chemical bath deposition
cost-effective processes
scalability
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
spellingShingle heterojunction
cadmium sulfide
lead selenide
chemical bath deposition
cost-effective processes
scalability
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
José Antonio Heredia-Cancino
Oscar Salcido
Ricardo Britto-Hurtado
Sayra Guadalupe Ruvalcaba-Manzo
Ramón Ochoa-Landín
Santos Jesús Castillo
CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
description Complete optoelectronic devices present major difficulties to be built by aqueous chemical deposition. In this work, a ITO/CdS/PbSe heterostructure was developed, depositing CdS over an ITO-coated substrate via a chemical bath deposition (CBD) technique. The next step involved the growth of a plumbonacrite film over CdS via CBD, where the film acted as a precursor film to be converted to PbSe via ion exchange. The characterization of each material involved in the heterostructure were as follows: the CdS thin films presented a hexagonal crystalline structure and bandgap of 2.42 eV; PbSe had a cubic structure and a bandgap of 0.34 eV. I vs. V measurements allowed the observation of the electrical behavior, which showed a change from an ohmic to diode response by applying a thermal annealing at 150 °C for 5 min. The forward bias of the diode response was in the order of 0.8 V, and the current-voltage characteristics were analyzed by using the modified Shockley model, obtaining an ideality factor of 2.47, being similar to a Schottky diode. Therefore, the reported process to synthesize an ITO/CdS/PbSe heterostructure by aqueous chemical methods was successful and could be used to develop optoelectronic devices.
format article
author José Antonio Heredia-Cancino
Oscar Salcido
Ricardo Britto-Hurtado
Sayra Guadalupe Ruvalcaba-Manzo
Ramón Ochoa-Landín
Santos Jesús Castillo
author_facet José Antonio Heredia-Cancino
Oscar Salcido
Ricardo Britto-Hurtado
Sayra Guadalupe Ruvalcaba-Manzo
Ramón Ochoa-Landín
Santos Jesús Castillo
author_sort José Antonio Heredia-Cancino
title CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
title_short CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
title_full CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
title_fullStr CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
title_full_unstemmed CdS/PbSe Heterojunction Made via Chemical Bath Deposition and Ionic Exchange Processes to Develop Low-Cost and Scalable Devices
title_sort cds/pbse heterojunction made via chemical bath deposition and ionic exchange processes to develop low-cost and scalable devices
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/fd5c5390b4c94b418d6a3ced8399f4aa
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