Resonant catalysis of thermally activated chemical reactions with vibrational polaritons

Strong coupling of molecular vibrations to an optical cavity may catalyze thermally activated reactions, showcasing the potential of polariton chemistry. Here, the authors provide a theoretical framework explaining the chemical kinetics deriving from transit through polaritonic and dark states.

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Detalles Bibliográficos
Autores principales: Jorge A. Campos-Gonzalez-Angulo, Raphael F. Ribeiro, Joel Yuen-Zhou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
Materias:
Q
Acceso en línea:https://doaj.org/article/fe00025ad0124883bb0c4638c0b4b1dd
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Descripción
Sumario:Strong coupling of molecular vibrations to an optical cavity may catalyze thermally activated reactions, showcasing the potential of polariton chemistry. Here, the authors provide a theoretical framework explaining the chemical kinetics deriving from transit through polaritonic and dark states.