Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application

Ameer Azam,1 Saeed Salem Babkair21Center of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia; 2Center of Nanotechnology, Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, Saudi ArabiaAbstract: Well-aligned and single-crystalline zinc oxide (ZnO) nanorod ar...

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Autores principales: Azam A, Babkair SS
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Publicado: Dove Medical Press 2014
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spelling oai:doaj.org-article:fe3f2a62203e49d5a9dd2d4ac9d640252021-12-02T02:10:30ZLow-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application1178-2013https://doaj.org/article/fe3f2a62203e49d5a9dd2d4ac9d640252014-04-01T00:00:00Zhttp://www.dovepress.com/low-temperature-growth-of-well-aligned-zinc-oxide-nanorod-arrays-on-si-a16579https://doaj.org/toc/1178-2013 Ameer Azam,1 Saeed Salem Babkair21Center of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia; 2Center of Nanotechnology, Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, Saudi ArabiaAbstract: Well-aligned and single-crystalline zinc oxide (ZnO) nanorod arrays were grown on silicon (Si) substrate using a wet chemical route for the photodegradation of organic dyes. Structural analysis using X-ray diffraction, high-resolution transmission electron microscopy, and selected area electron diffraction confirmed the formation of ZnO nanorods grown preferentially oriented in the (001) direction and with a single phase nature with a wurtzite structure. Field emission scanning electron microscopy and transmission electron microscopy micrographs showed that the length and diameter of the well-aligned rods were about ~350–400 nm and ~80–90 nm, respectively. Raman scattering spectra of ZnO nanorod arrays revealed the characteristic E2 (high) mode that is related to the vibration of oxygen atoms in the wurtzite ZnO. The photodegradation of methylene blue (MB) using ZnO nanorod arrays was performed under ultraviolet light irradiation. The results of photodegradation showed that ZnO nanorod arrays were capable of degrading ~80% of MB within 60 minutes of irradiation, whereas ~92% of degradation was achieved in 120 minutes. Complete degradation of MB was observed after 270 minutes of irradiation time. Owing to enhanced photocatalytic degradation efficiency and low-temperature growth method, prepared ZnO nanorod arrays may open up the possibility for the successful utilization of ZnO nanorod arrays as a future photocatalyst for environmental remediation.Keywords: ZnO, nanorods, XRD, photodegradationAzam ABabkair SSDove Medical PressarticleMedicine (General)R5-920ENInternational Journal of Nanomedicine, Vol 2014, Iss Issue 1, Pp 2109-2115 (2014)
institution DOAJ
collection DOAJ
language EN
topic Medicine (General)
R5-920
spellingShingle Medicine (General)
R5-920
Azam A
Babkair SS
Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
description Ameer Azam,1 Saeed Salem Babkair21Center of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia; 2Center of Nanotechnology, Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, Saudi ArabiaAbstract: Well-aligned and single-crystalline zinc oxide (ZnO) nanorod arrays were grown on silicon (Si) substrate using a wet chemical route for the photodegradation of organic dyes. Structural analysis using X-ray diffraction, high-resolution transmission electron microscopy, and selected area electron diffraction confirmed the formation of ZnO nanorods grown preferentially oriented in the (001) direction and with a single phase nature with a wurtzite structure. Field emission scanning electron microscopy and transmission electron microscopy micrographs showed that the length and diameter of the well-aligned rods were about ~350–400 nm and ~80–90 nm, respectively. Raman scattering spectra of ZnO nanorod arrays revealed the characteristic E2 (high) mode that is related to the vibration of oxygen atoms in the wurtzite ZnO. The photodegradation of methylene blue (MB) using ZnO nanorod arrays was performed under ultraviolet light irradiation. The results of photodegradation showed that ZnO nanorod arrays were capable of degrading ~80% of MB within 60 minutes of irradiation, whereas ~92% of degradation was achieved in 120 minutes. Complete degradation of MB was observed after 270 minutes of irradiation time. Owing to enhanced photocatalytic degradation efficiency and low-temperature growth method, prepared ZnO nanorod arrays may open up the possibility for the successful utilization of ZnO nanorod arrays as a future photocatalyst for environmental remediation.Keywords: ZnO, nanorods, XRD, photodegradation
format article
author Azam A
Babkair SS
author_facet Azam A
Babkair SS
author_sort Azam A
title Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
title_short Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
title_full Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
title_fullStr Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
title_full_unstemmed Low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
title_sort low-temperature growth of well-aligned zinc oxide nanorod arrays on silicon substrate and their photocatalytic application
publisher Dove Medical Press
publishDate 2014
url https://doaj.org/article/fe3f2a62203e49d5a9dd2d4ac9d64025
work_keys_str_mv AT azama lowtemperaturegrowthofwellalignedzincoxidenanorodarraysonsiliconsubstrateandtheirphotocatalyticapplication
AT babkairss lowtemperaturegrowthofwellalignedzincoxidenanorodarraysonsiliconsubstrateandtheirphotocatalyticapplication
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