Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Entha...
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Turkish Chemical Society
2021
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oai:doaj.org-article:fe72a64eeb86466ebc51b633747af57c2021-11-20T09:45:41Z Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium 10.18596/jotcsa.9723252149-0120https://doaj.org/article/fe72a64eeb86466ebc51b633747af57c2021-11-01T00:00:00Zhttps://dergipark.org.tr/tr/pub/jotcsa/issue/64621/972325https://doaj.org/toc/2149-0120Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Enthalpy and entropy of the reaction has been calculated and found that the inhibition process follows physical adsorption on the surface. Adsorption process follows langmuir’s adsorption isotherm. The inhibition behavior on mild steel surface is supplemented by the surface study through atomic force microscopy and found that the inhibited surface have less roughness than the uninhibited surface.Sudhish KUMAR SHUKLASomya TANWERTurkish Chemical Societyarticleeco-friendly inhibitorsweight losseisafmChemistryQD1-999ENJournal of the Turkish Chemical Society, Section A: Chemistry, Vol 8, Iss 4, Pp 1099 -1110 (2021) |
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eco-friendly inhibitors weight loss eis afm Chemistry QD1-999 Sudhish KUMAR SHUKLA Somya TANWER Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
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Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Enthalpy and entropy of the reaction has been calculated and found that the inhibition process follows physical adsorption on the surface. Adsorption process follows langmuir’s adsorption isotherm. The inhibition behavior on mild steel surface is supplemented by the surface study through atomic force microscopy and found that the inhibited surface have less roughness than the uninhibited surface. |
format |
article |
author |
Sudhish KUMAR SHUKLA Somya TANWER |
author_facet |
Sudhish KUMAR SHUKLA Somya TANWER |
author_sort |
Sudhish KUMAR SHUKLA |
title |
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
title_short |
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
title_full |
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
title_fullStr |
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
title_full_unstemmed |
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium |
title_sort |
evaluation of corrosion inhibition properties of pharmaceutically active compound cefotaxime sodium on mild steel surface in sulfuric acid medium |
publisher |
Turkish Chemical Society |
publishDate |
2021 |
url |
https://doaj.org/article/fe72a64eeb86466ebc51b633747af57c |
work_keys_str_mv |
AT sudhishkumarshukla evaluationofcorrosioninhibitionpropertiesofpharmaceuticallyactivecompoundcefotaximesodiumonmildsteelsurfaceinsulfuricacidmedium AT somyatanwer evaluationofcorrosioninhibitionpropertiesofpharmaceuticallyactivecompoundcefotaximesodiumonmildsteelsurfaceinsulfuricacidmedium |
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1718419460945084416 |