Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium

Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Entha...

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Autores principales: Sudhish KUMAR SHUKLA, Somya TANWER
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Lenguaje:EN
Publicado: Turkish Chemical Society 2021
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Acceso en línea:https://doaj.org/article/fe72a64eeb86466ebc51b633747af57c
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spelling oai:doaj.org-article:fe72a64eeb86466ebc51b633747af57c2021-11-20T09:45:41Z Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium 10.18596/jotcsa.9723252149-0120https://doaj.org/article/fe72a64eeb86466ebc51b633747af57c2021-11-01T00:00:00Zhttps://dergipark.org.tr/tr/pub/jotcsa/issue/64621/972325https://doaj.org/toc/2149-0120Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Enthalpy and entropy of the reaction has been calculated and found that the inhibition process follows physical adsorption on the surface. Adsorption process follows langmuir’s adsorption isotherm. The inhibition behavior on mild steel surface is supplemented by the surface study through atomic force microscopy and found that the inhibited surface have less roughness than the uninhibited surface.Sudhish KUMAR SHUKLASomya TANWERTurkish Chemical Societyarticleeco-friendly inhibitorsweight losseisafmChemistryQD1-999ENJournal of the Turkish Chemical Society, Section A: Chemistry, Vol 8, Iss 4, Pp 1099 -1110 (2021)
institution DOAJ
collection DOAJ
language EN
topic eco-friendly inhibitors
weight loss
eis
afm
Chemistry
QD1-999
spellingShingle eco-friendly inhibitors
weight loss
eis
afm
Chemistry
QD1-999
Sudhish KUMAR SHUKLA
Somya TANWER
Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
description Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Enthalpy and entropy of the reaction has been calculated and found that the inhibition process follows physical adsorption on the surface. Adsorption process follows langmuir’s adsorption isotherm. The inhibition behavior on mild steel surface is supplemented by the surface study through atomic force microscopy and found that the inhibited surface have less roughness than the uninhibited surface.
format article
author Sudhish KUMAR SHUKLA
Somya TANWER
author_facet Sudhish KUMAR SHUKLA
Somya TANWER
author_sort Sudhish KUMAR SHUKLA
title Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
title_short Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
title_full Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
title_fullStr Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
title_full_unstemmed Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium
title_sort evaluation of corrosion inhibition properties of pharmaceutically active compound cefotaxime sodium on mild steel surface in sulfuric acid medium
publisher Turkish Chemical Society
publishDate 2021
url https://doaj.org/article/fe72a64eeb86466ebc51b633747af57c
work_keys_str_mv AT sudhishkumarshukla evaluationofcorrosioninhibitionpropertiesofpharmaceuticallyactivecompoundcefotaximesodiumonmildsteelsurfaceinsulfuricacidmedium
AT somyatanwer evaluationofcorrosioninhibitionpropertiesofpharmaceuticallyactivecompoundcefotaximesodiumonmildsteelsurfaceinsulfuricacidmedium
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