An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides

An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides

Investigating unusual organometallic pathways may help to efficiently control product selectivity in homogeneous catalysis. Here, the authors report the hydroarylation of aromatic amides with norbornene derivatives and propose the formation of a rhodium-carbene intermediate leading to rarely observe...

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Autores principales: Kaname Shibata, Satoko Natsui, Mamoru Tobisu, Yoshiya Fukumoto, Naoto Chatani
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/fe975581af0e40b3840956db9500644a
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spelling oai:doaj.org-article:fe975581af0e40b3840956db9500644a2021-12-02T17:06:29ZAn unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides10.1038/s41467-017-01531-22041-1723https://doaj.org/article/fe975581af0e40b3840956db9500644a2017-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01531-2https://doaj.org/toc/2041-1723Investigating unusual organometallic pathways may help to efficiently control product selectivity in homogeneous catalysis. Here, the authors report the hydroarylation of aromatic amides with norbornene derivatives and propose the formation of a rhodium-carbene intermediate leading to rarely observed endo-products.Kaname ShibataSatoko NatsuiMamoru TobisuYoshiya FukumotoNaoto ChataniNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kaname Shibata
Satoko Natsui
Mamoru Tobisu
Yoshiya Fukumoto
Naoto Chatani
An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
description Investigating unusual organometallic pathways may help to efficiently control product selectivity in homogeneous catalysis. Here, the authors report the hydroarylation of aromatic amides with norbornene derivatives and propose the formation of a rhodium-carbene intermediate leading to rarely observed endo-products.
format article
author Kaname Shibata
Satoko Natsui
Mamoru Tobisu
Yoshiya Fukumoto
Naoto Chatani
author_facet Kaname Shibata
Satoko Natsui
Mamoru Tobisu
Yoshiya Fukumoto
Naoto Chatani
author_sort Kaname Shibata
title An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
title_short An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
title_full An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
title_fullStr An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
title_full_unstemmed An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides
title_sort unusual endo-selective c-h hydroarylationof norbornene by the rh(i)-catalyzed reactionof benzamides
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/fe975581af0e40b3840956db9500644a
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AT mamorutobisu anunusualendoselectivechhydroarylationofnorbornenebytherhicatalyzedreactionofbenzamides
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