Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation

Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear ce...

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Autores principales:	Cornelius Krull, Marina Castelli, Prokop Hapala, Dhaneesh Kumar, Anton Tadich, Martina Capsoni, Mark T. Edmonds, Jack Hellerstedt, Sarah A. Burke, Pavel Jelinek, Agustin Schiffrin
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ff2716a9ecec41f0b9f10b8ab821f7b8
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spelling	oai:doaj.org-article:ff2716a9ecec41f0b9f10b8ab821f7b82021-12-02T17:31:46ZIron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation10.1038/s41467-018-05543-42041-1723https://doaj.org/article/ff2716a9ecec41f0b9f10b8ab821f7b82018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05543-4https://doaj.org/toc/2041-1723Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear centre suggests a catalytically active core.Cornelius KrullMarina CastelliProkop HapalaDhaneesh KumarAnton TadichMartina CapsoniMark T. EdmondsJack HellerstedtSarah A. BurkePavel JelinekAgustin SchiffrinNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
description	Polynuclear metal-organic coordination complexes are often inaccessible by traditional synthetic chemistry methods. Here, the authors use on-surface supramolecular chemistry to form a planar trinuclear Fe complex, in which an accumulation of electrons around the positive mixed-valence polynuclear centre suggests a catalytically active core.
format	article
author	Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin
author_facet	Cornelius Krull Marina Castelli Prokop Hapala Dhaneesh Kumar Anton Tadich Martina Capsoni Mark T. Edmonds Jack Hellerstedt Sarah A. Burke Pavel Jelinek Agustin Schiffrin
author_sort	Cornelius Krull
title	Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
title_short	Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
title_full	Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
title_fullStr	Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
title_full_unstemmed	Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
title_sort	iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/ff2716a9ecec41f0b9f10b8ab821f7b8
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Iron-based trinuclear metal-organic nanostructures on a surface with local charge accumulation

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