Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles

Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ion...

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Autores principales: Jinshui Liu, Kasipandi Vellaisamy, Guanjun Yang, Chung-Hang Leung, Dik-Lung Ma
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/ff7b1cff29984249b4508c017e4688f9
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spelling oai:doaj.org-article:ff7b1cff29984249b4508c017e4688f92021-12-02T16:06:03ZLuminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles10.1038/s41598-017-03952-x2045-2322https://doaj.org/article/ff7b1cff29984249b4508c017e4688f92017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-03952-xhttps://doaj.org/toc/2045-2322Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ions to form Ag(I) and Ag/Hg amalgam. The luminescence intensity of 1 increased in accord with an increased Hg(II) concentration ranging from 0 nM to 180 nM, with the detection limit of 5 nM. This approach offers an innovative method for the quantification of Hg(II).Jinshui LiuKasipandi VellaisamyGuanjun YangChung-Hang LeungDik-Lung MaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Jinshui Liu
Kasipandi Vellaisamy
Guanjun Yang
Chung-Hang Leung
Dik-Lung Ma
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
description Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ions to form Ag(I) and Ag/Hg amalgam. The luminescence intensity of 1 increased in accord with an increased Hg(II) concentration ranging from 0 nM to 180 nM, with the detection limit of 5 nM. This approach offers an innovative method for the quantification of Hg(II).
format article
author Jinshui Liu
Kasipandi Vellaisamy
Guanjun Yang
Chung-Hang Leung
Dik-Lung Ma
author_facet Jinshui Liu
Kasipandi Vellaisamy
Guanjun Yang
Chung-Hang Leung
Dik-Lung Ma
author_sort Jinshui Liu
title Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
title_short Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
title_full Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
title_fullStr Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
title_full_unstemmed Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
title_sort luminescent turn-on detection of hg(ii) via the quenching of an iridium(iii) complex by hg(ii)-mediated silver nanoparticles
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/ff7b1cff29984249b4508c017e4688f9
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AT kasipandivellaisamy luminescentturnondetectionofhgiiviathequenchingofaniridiumiiicomplexbyhgiimediatedsilvernanoparticles
AT guanjunyang luminescentturnondetectionofhgiiviathequenchingofaniridiumiiicomplexbyhgiimediatedsilvernanoparticles
AT chunghangleung luminescentturnondetectionofhgiiviathequenchingofaniridiumiiicomplexbyhgiimediatedsilvernanoparticles
AT diklungma luminescentturnondetectionofhgiiviathequenchingofaniridiumiiicomplexbyhgiimediatedsilvernanoparticles
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