Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles
Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ion...
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Nature Portfolio
2017
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oai:doaj.org-article:ff7b1cff29984249b4508c017e4688f92021-12-02T16:06:03ZLuminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles10.1038/s41598-017-03952-x2045-2322https://doaj.org/article/ff7b1cff29984249b4508c017e4688f92017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-03952-xhttps://doaj.org/toc/2045-2322Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ions to form Ag(I) and Ag/Hg amalgam. The luminescence intensity of 1 increased in accord with an increased Hg(II) concentration ranging from 0 nM to 180 nM, with the detection limit of 5 nM. This approach offers an innovative method for the quantification of Hg(II).Jinshui LiuKasipandi VellaisamyGuanjun YangChung-Hang LeungDik-Lung MaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017) |
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Medicine R Science Q Jinshui Liu Kasipandi Vellaisamy Guanjun Yang Chung-Hang Leung Dik-Lung Ma Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
description |
Abstract A novel luminescent turn-on detection method for Hg(II) was developed. The method was based on the silver nanoparticle (AgNP)-mediated quenching of Ir(III) complex 1. The addition of Hg(II) ions causes the luminescence of complex 1 to be recovered due to the oxidation of AgNPs by Hg(II) ions to form Ag(I) and Ag/Hg amalgam. The luminescence intensity of 1 increased in accord with an increased Hg(II) concentration ranging from 0 nM to 180 nM, with the detection limit of 5 nM. This approach offers an innovative method for the quantification of Hg(II). |
format |
article |
author |
Jinshui Liu Kasipandi Vellaisamy Guanjun Yang Chung-Hang Leung Dik-Lung Ma |
author_facet |
Jinshui Liu Kasipandi Vellaisamy Guanjun Yang Chung-Hang Leung Dik-Lung Ma |
author_sort |
Jinshui Liu |
title |
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
title_short |
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
title_full |
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
title_fullStr |
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
title_full_unstemmed |
Luminescent turn-on detection of Hg(II) via the quenching of an iridium(III) complex by Hg(II)-mediated silver nanoparticles |
title_sort |
luminescent turn-on detection of hg(ii) via the quenching of an iridium(iii) complex by hg(ii)-mediated silver nanoparticles |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/ff7b1cff29984249b4508c017e4688f9 |
work_keys_str_mv |
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1718385187505569792 |