Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation

The simultaneous construction of two different types of chiralities is challenging. Here, the authors report a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocene derivatives, which enabled the simultaneous construction of axial and planar chirality.

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Autores principales: Pei-Chao Zhang, Yin-Lin Li, Jiafeng He, Hai-Hong Wu, Zhiming Li, Junliang Zhang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/ff7b6d4792e14b2eabcb2f9f7655730f
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Sumario:The simultaneous construction of two different types of chiralities is challenging. Here, the authors report a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocene derivatives, which enabled the simultaneous construction of axial and planar chirality.