Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation

The simultaneous construction of two different types of chiralities is challenging. Here, the authors report a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocene derivatives, which enabled the simultaneous construction of axial and planar chirality.

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Autores principales:	Pei-Chao Zhang, Yin-Lin Li, Jiafeng He, Hai-Hong Wu, Zhiming Li, Junliang Zhang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ff7b6d4792e14b2eabcb2f9f7655730f
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spelling	oai:doaj.org-article:ff7b6d4792e14b2eabcb2f9f7655730f2021-12-02T18:46:58ZSimultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation10.1038/s41467-021-24678-52041-1723https://doaj.org/article/ff7b6d4792e14b2eabcb2f9f7655730f2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24678-5https://doaj.org/toc/2041-1723The simultaneous construction of two different types of chiralities is challenging. Here, the authors report a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocene derivatives, which enabled the simultaneous construction of axial and planar chirality.Pei-Chao ZhangYin-Lin LiJiafeng HeHai-Hong WuZhiming LiJunliang ZhangNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Pei-Chao Zhang Yin-Lin Li Jiafeng He Hai-Hong Wu Zhiming Li Junliang Zhang Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
description	The simultaneous construction of two different types of chiralities is challenging. Here, the authors report a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocene derivatives, which enabled the simultaneous construction of axial and planar chirality.
format	article
author	Pei-Chao Zhang Yin-Lin Li Jiafeng He Hai-Hong Wu Zhiming Li Junliang Zhang
author_facet	Pei-Chao Zhang Yin-Lin Li Jiafeng He Hai-Hong Wu Zhiming Li Junliang Zhang
author_sort	Pei-Chao Zhang
title	Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
title_short	Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
title_full	Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
title_fullStr	Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
title_full_unstemmed	Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation
title_sort	simultaneous construction of axial and planar chirality by gold/ty-phos-catalyzed asymmetric hydroarylation
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/ff7b6d4792e14b2eabcb2f9f7655730f
work_keys_str_mv	AT peichaozhang simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation AT yinlinli simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation AT jiafenghe simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation AT haihongwu simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation AT zhimingli simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation AT junliangzhang simultaneousconstructionofaxialandplanarchiralitybygoldtyphoscatalyzedasymmetrichydroarylation
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Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation

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