High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent
Abstract Deep eutectic solvent (DES) was applied to the solvent of thermocell and high Seebeck coefficient (S e) of the thermocell was achieved at high-temperatures operation. The S e of a redox couple of ferricyanide and ferrocyanide ([Fe(CN)6]3−/4−) reaches − 1.67 mV/K in a DES consisting of ethyl...
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Nature Portfolio
2021
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oai:doaj.org-article:ffd4d28b63fe497a84d1fa91f5e253d92021-12-02T14:58:14ZHigh seebeck coefficient in middle-temperature thermocell with deep eutectic solvent10.1038/s41598-021-91419-52045-2322https://doaj.org/article/ffd4d28b63fe497a84d1fa91f5e253d92021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-91419-5https://doaj.org/toc/2045-2322Abstract Deep eutectic solvent (DES) was applied to the solvent of thermocell and high Seebeck coefficient (S e) of the thermocell was achieved at high-temperatures operation. The S e of a redox couple of ferricyanide and ferrocyanide ([Fe(CN)6]3−/4−) reaches − 1.67 mV/K in a DES consisting of ethylene glycol and choline chloride. Spectroscopic analysis reveals that this is due to the strong interactions between the redox couple and the DES. Furthermore, the cell can operate over a wide temperature range of 135–165 °C. This result is a desired feature for waste-heat recovery applications.Naura Fakhira AntariksaTeppei YamadaNobuo KimizukaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-7 (2021) |
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Medicine R Science Q |
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Medicine R Science Q Naura Fakhira Antariksa Teppei Yamada Nobuo Kimizuka High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| description |
Abstract Deep eutectic solvent (DES) was applied to the solvent of thermocell and high Seebeck coefficient (S e) of the thermocell was achieved at high-temperatures operation. The S e of a redox couple of ferricyanide and ferrocyanide ([Fe(CN)6]3−/4−) reaches − 1.67 mV/K in a DES consisting of ethylene glycol and choline chloride. Spectroscopic analysis reveals that this is due to the strong interactions between the redox couple and the DES. Furthermore, the cell can operate over a wide temperature range of 135–165 °C. This result is a desired feature for waste-heat recovery applications. |
| format |
article |
| author |
Naura Fakhira Antariksa Teppei Yamada Nobuo Kimizuka |
| author_facet |
Naura Fakhira Antariksa Teppei Yamada Nobuo Kimizuka |
| author_sort |
Naura Fakhira Antariksa |
| title |
High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| title_short |
High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| title_full |
High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| title_fullStr |
High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| title_full_unstemmed |
High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| title_sort |
high seebeck coefficient in middle-temperature thermocell with deep eutectic solvent |
| publisher |
Nature Portfolio |
| publishDate |
2021 |
| url |
https://doaj.org/article/ffd4d28b63fe497a84d1fa91f5e253d9 |
| work_keys_str_mv |
AT naurafakhiraantariksa highseebeckcoefficientinmiddletemperaturethermocellwithdeepeutecticsolvent AT teppeiyamada highseebeckcoefficientinmiddletemperaturethermocellwithdeepeutecticsolvent AT nobuokimizuka highseebeckcoefficientinmiddletemperaturethermocellwithdeepeutecticsolvent |
| _version_ |
1718389363735265280 |