SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS

Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute...

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Autores principales: PERIC,IVAN M., RIVAS,BERNABE L., POOLEY,AMALIA, RIFFFO,ELIZARDO, BASAEZ,LUIS A.
Lenguaje:English
Publicado: Sociedad Chilena de Química 1999
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16441999000300011
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spelling oai:scielo:S0366-164419990003000112000-10-13SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESISPERIC,IVAN M.RIVAS,BERNABE L.POOLEY,AMALIARIFFFO,ELIZARDOBASAEZ,LUIS A. Capillary zone electrophoresis polymers polyelectrolytes acrylamide acrylic acid Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute value of the electrophoretic mobility is strongly dependent of the linear charge density of the copolymer in agrement with the Manning's counterion condensation theory. Analyses were performed in under 15 minutes using a phosphate or borate bufferinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.44 n.3 19991999-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16441999000300011en10.4067/S0366-16441999000300011
institution Scielo Chile
collection Scielo Chile
language English
topic Capillary zone electrophoresis
polymers
polyelectrolytes
acrylamide
acrylic acid
spellingShingle Capillary zone electrophoresis
polymers
polyelectrolytes
acrylamide
acrylic acid
PERIC,IVAN M.
RIVAS,BERNABE L.
POOLEY,AMALIA
RIFFFO,ELIZARDO
BASAEZ,LUIS A.
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
description Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute value of the electrophoretic mobility is strongly dependent of the linear charge density of the copolymer in agrement with the Manning's counterion condensation theory. Analyses were performed in under 15 minutes using a phosphate or borate buffer
author PERIC,IVAN M.
RIVAS,BERNABE L.
POOLEY,AMALIA
RIFFFO,ELIZARDO
BASAEZ,LUIS A.
author_facet PERIC,IVAN M.
RIVAS,BERNABE L.
POOLEY,AMALIA
RIFFFO,ELIZARDO
BASAEZ,LUIS A.
author_sort PERIC,IVAN M.
title SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
title_short SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
title_full SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
title_fullStr SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
title_full_unstemmed SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
title_sort separation of copolymers of variable compositions by capillary zone electrophoresis
publisher Sociedad Chilena de Química
publishDate 1999
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16441999000300011
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