SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS
Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute...
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Sociedad Chilena de Química
1999
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oai:scielo:S0366-164419990003000112000-10-13SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESISPERIC,IVAN M.RIVAS,BERNABE L.POOLEY,AMALIARIFFFO,ELIZARDOBASAEZ,LUIS A. Capillary zone electrophoresis polymers polyelectrolytes acrylamide acrylic acid Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute value of the electrophoretic mobility is strongly dependent of the linear charge density of the copolymer in agrement with the Manning's counterion condensation theory. Analyses were performed in under 15 minutes using a phosphate or borate bufferinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.44 n.3 19991999-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16441999000300011en10.4067/S0366-16441999000300011 |
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Scielo Chile |
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Scielo Chile |
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English |
topic |
Capillary zone electrophoresis polymers polyelectrolytes acrylamide acrylic acid |
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Capillary zone electrophoresis polymers polyelectrolytes acrylamide acrylic acid PERIC,IVAN M. RIVAS,BERNABE L. POOLEY,AMALIA RIFFFO,ELIZARDO BASAEZ,LUIS A. SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
description |
Capillary zone electrophoresis (CZE) analysis of several copolymers obtained by radical copolymerization of acrylamide and N,N'-dimethylacrylamide using acrylic acid and 1-vinyl-2-pyrrolidone as comonomers under different feed molar ratios had been carried out. Results demonstrate that absolute value of the electrophoretic mobility is strongly dependent of the linear charge density of the copolymer in agrement with the Manning's counterion condensation theory. Analyses were performed in under 15 minutes using a phosphate or borate buffer |
author |
PERIC,IVAN M. RIVAS,BERNABE L. POOLEY,AMALIA RIFFFO,ELIZARDO BASAEZ,LUIS A. |
author_facet |
PERIC,IVAN M. RIVAS,BERNABE L. POOLEY,AMALIA RIFFFO,ELIZARDO BASAEZ,LUIS A. |
author_sort |
PERIC,IVAN M. |
title |
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
title_short |
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
title_full |
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
title_fullStr |
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
title_full_unstemmed |
SEPARATION OF COPOLYMERS OF VARIABLE COMPOSITIONS BY CAPILLARY ZONE ELECTROPHORESIS |
title_sort |
separation of copolymers of variable compositions by capillary zone electrophoresis |
publisher |
Sociedad Chilena de Química |
publishDate |
1999 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16441999000300011 |
work_keys_str_mv |
AT pericivanm separationofcopolymersofvariablecompositionsbycapillaryzoneelectrophoresis AT rivasbernabel separationofcopolymersofvariablecompositionsbycapillaryzoneelectrophoresis AT pooleyamalia separationofcopolymersofvariablecompositionsbycapillaryzoneelectrophoresis AT rifffoelizardo separationofcopolymersofvariablecompositionsbycapillaryzoneelectrophoresis AT basaezluisa separationofcopolymersofvariablecompositionsbycapillaryzoneelectrophoresis |
_version_ |
1718438094911307776 |