NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES

The electrochemical nitroreduction of nitrofurantoin has been studiedon carbon paste and glassy carbon electrodes. We can observe a monoelectronicreversible couple ArNO2/ArNO2.- and anirreversible peak due to the further reduction of nitro radical to thehidroxilamine via three electrons. According t...

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Autores principales:	MERINO,M., CARBAJO,J., NUÑEZ-VERGARA,L.J., SQUELLA,J.A.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2000
Materias:	Electroreduction carbon paste electrode glassy carbon electrode nitrofurantoin
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000100013
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spelling	oai:scielo:S0366-164420000001000132000-09-25NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODESMERINO,M.CARBAJO,J.NUÑEZ-VERGARA,L.J.SQUELLA,J.A. Electroreduction carbon paste electrode glassy carbon electrode nitrofurantoin The electrochemical nitroreduction of nitrofurantoin has been studiedon carbon paste and glassy carbon electrodes. We can observe a monoelectronicreversible couple ArNO2/ArNO2.- and anirreversible peak due to the further reduction of nitro radical to thehidroxilamine via three electrons. According to the experimental results, the reduction process shows atypical behavior of an EC mechanism. The k2 obtained values showed that the nitroradical anion was better stabilized on carbon paste electrodeinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.1 20002000-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000100013en10.4067/S0366-16442000000100013
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Electroreduction carbon paste electrode glassy carbon electrode nitrofurantoin
spellingShingle	Electroreduction carbon paste electrode glassy carbon electrode nitrofurantoin MERINO,M. CARBAJO,J. NUÑEZ-VERGARA,L.J. SQUELLA,J.A. NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
description	The electrochemical nitroreduction of nitrofurantoin has been studiedon carbon paste and glassy carbon electrodes. We can observe a monoelectronicreversible couple ArNO2/ArNO2.- and anirreversible peak due to the further reduction of nitro radical to thehidroxilamine via three electrons. According to the experimental results, the reduction process shows atypical behavior of an EC mechanism. The k2 obtained values showed that the nitroradical anion was better stabilized on carbon paste electrode
author	MERINO,M. CARBAJO,J. NUÑEZ-VERGARA,L.J. SQUELLA,J.A.
author_facet	MERINO,M. CARBAJO,J. NUÑEZ-VERGARA,L.J. SQUELLA,J.A.
author_sort	MERINO,M.
title	NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
title_short	NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
title_full	NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
title_fullStr	NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
title_full_unstemmed	NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES
title_sort	nitroradical anion formation from nitrofurantoin in carbon electrodes
publisher	Sociedad Chilena de Química
publishDate	2000
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000100013
work_keys_str_mv	AT merinom nitroradicalanionformationfromnitrofurantoinincarbonelectrodes AT carbajoj nitroradicalanionformationfromnitrofurantoinincarbonelectrodes AT nunezvergaralj nitroradicalanionformationfromnitrofurantoinincarbonelectrodes AT squellaja nitroradicalanionformationfromnitrofurantoinincarbonelectrodes
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NITRORADICAL ANION FORMATION FROM NITROFURANTOIN IN CARBON ELECTRODES

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