HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS

Reaction of dinuclear complex [{(h6-C6Me6)Ru(µ-Cl)Cl} 2] with the ligand NH(PPh2)2 in 1:2 molar ratio affords the mononuclear complex [(h6-C6Me6)RuCl 2{h1-(PPh2)2NH}](1) which in turn reacts with AgPF6 to yield the cationic compound [(h6-C6Me6)RuCl{h 2-(PPh2)2NH}]PF6 (2). Complex 3 reacts with KOBut...

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Autores principales:	VALDERRAMA,MAURICIO, CONTRERAS,RAUL, ARANCIBIA,VERONICA, MUÑOZ,PATRICIO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2000
Materias:	Ruthenium bis(diphenylphosphine)anime complexes bis(diphenylphosphine) methylamine complexes hexamethylbenzene complexes synthesis
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200009
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spelling	oai:scielo:S0366-164420000002000092000-08-25HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDSVALDERRAMA,MAURICIOCONTRERAS,RAULARANCIBIA,VERONICAMUÑOZ,PATRICIO Ruthenium bis(diphenylphosphine)anime complexes bis(diphenylphosphine) methylamine complexes hexamethylbenzene complexes synthesis Reaction of dinuclear complex [{(h6-C6Me6)Ru(µ-Cl)Cl} 2] with the ligand NH(PPh2)2 in 1:2 molar ratio affords the mononuclear complex [(h6-C6Me6)RuCl 2{h1-(PPh2)2NH}](1) which in turn reacts with AgPF6 to yield the cationic compound [(h6-C6Me6)RuCl{h 2-(PPh2)2NH}]PF6 (2). Complex 3 reacts with KOBut to give the neutral complex [(h6-C6Me6)RuCl{h 2-(PPh2)2N}](3). The anionic ligand of complex 3 reacts easily with HBF4 regenerating the starting complex and with MeI by N-methylation of the chelate ligand. The non coordinating P atom of complex 1 reacts with sulfur or selenium to form the P-coordinate monosulphide or selenide ligands, [{(h6-C6Me6)RuCl 2{h1PPh2NHP(E)Ph2 }] (5,6). The treatment of complexes 5 and 6 with AgPF6 affords cationic (7,8) or neutral (9,10) complexes depending of the solvent used. The neutral complex 9 can be N-derivatized by reaction with MeIinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.2 20002000-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200009en10.4067/S0366-16442000000200009
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Ruthenium bis(diphenylphosphine)anime complexes bis(diphenylphosphine) methylamine complexes hexamethylbenzene complexes synthesis
spellingShingle	Ruthenium bis(diphenylphosphine)anime complexes bis(diphenylphosphine) methylamine complexes hexamethylbenzene complexes synthesis VALDERRAMA,MAURICIO CONTRERAS,RAUL ARANCIBIA,VERONICA MUÑOZ,PATRICIO HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
description	Reaction of dinuclear complex [{(h6-C6Me6)Ru(µ-Cl)Cl} 2] with the ligand NH(PPh2)2 in 1:2 molar ratio affords the mononuclear complex [(h6-C6Me6)RuCl 2{h1-(PPh2)2NH}](1) which in turn reacts with AgPF6 to yield the cationic compound [(h6-C6Me6)RuCl{h 2-(PPh2)2NH}]PF6 (2). Complex 3 reacts with KOBut to give the neutral complex [(h6-C6Me6)RuCl{h 2-(PPh2)2N}](3). The anionic ligand of complex 3 reacts easily with HBF4 regenerating the starting complex and with MeI by N-methylation of the chelate ligand. The non coordinating P atom of complex 1 reacts with sulfur or selenium to form the P-coordinate monosulphide or selenide ligands, [{(h6-C6Me6)RuCl 2{h1PPh2NHP(E)Ph2 }] (5,6). The treatment of complexes 5 and 6 with AgPF6 affords cationic (7,8) or neutral (9,10) complexes depending of the solvent used. The neutral complex 9 can be N-derivatized by reaction with MeI
author	VALDERRAMA,MAURICIO CONTRERAS,RAUL ARANCIBIA,VERONICA MUÑOZ,PATRICIO
author_facet	VALDERRAMA,MAURICIO CONTRERAS,RAUL ARANCIBIA,VERONICA MUÑOZ,PATRICIO
author_sort	VALDERRAMA,MAURICIO
title	HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
title_short	HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
title_full	HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
title_fullStr	HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
title_full_unstemmed	HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS
title_sort	hexamethylbenzeneruthenium(ii) complexes containing bis(diphenylphosphine)amine and their sulphur or selenium derivatives as ligands
publisher	Sociedad Chilena de Química
publishDate	2000
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200009
work_keys_str_mv	AT valderramamauricio hexamethylbenzenerutheniumiicomplexescontainingbisdiphenylphosphineamineandtheirsulphurorseleniumderivativesasligands AT contrerasraul hexamethylbenzenerutheniumiicomplexescontainingbisdiphenylphosphineamineandtheirsulphurorseleniumderivativesasligands AT arancibiaveronica hexamethylbenzenerutheniumiicomplexescontainingbisdiphenylphosphineamineandtheirsulphurorseleniumderivativesasligands AT munozpatricio hexamethylbenzenerutheniumiicomplexescontainingbisdiphenylphosphineamineandtheirsulphurorseleniumderivativesasligands
_version_	1718438108782919680

HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS

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