INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES

Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a...

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Autores principales: CALVO,VICTOR, CORTÉS,PIEDAD, MORENO,YANKO, VEGA,ANDRES, SPODINE,EVGENIA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2000
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200013
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spelling oai:scielo:S0366-164420000002000132000-08-25INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXESCALVO,VICTORCORTÉS,PIEDADMORENO,YANKOVEGA,ANDRESSPODINE,EVGENIA Hydrogen bonding magnetic exchange copper(II) trifluoroacetate Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a = 6.067(1)Å, b = 12.153(3)Å, c = 15.057(3)Å, <FONT FACE=Symbol>a</FONT>= 100.09(2), <FONT FACE=Symbol>b</FONT>= 99.15(2), <FONT FACE=Symbol>g</FONT>= 101.00(2) and Z = 2. The single crystal EPR spectrum of (1) shows to signals (ginfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.2 20002000-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200013en10.4067/S0366-16442000000200013
institution Scielo Chile
collection Scielo Chile
language English
topic Hydrogen bonding
magnetic exchange
copper(II)
trifluoroacetate
spellingShingle Hydrogen bonding
magnetic exchange
copper(II)
trifluoroacetate
CALVO,VICTOR
CORTÉS,PIEDAD
MORENO,YANKO
VEGA,ANDRES
SPODINE,EVGENIA
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
description Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a = 6.067(1)Å, b = 12.153(3)Å, c = 15.057(3)Å, <FONT FACE=Symbol>a</FONT>= 100.09(2), <FONT FACE=Symbol>b</FONT>= 99.15(2), <FONT FACE=Symbol>g</FONT>= 101.00(2) and Z = 2. The single crystal EPR spectrum of (1) shows to signals (g
author CALVO,VICTOR
CORTÉS,PIEDAD
MORENO,YANKO
VEGA,ANDRES
SPODINE,EVGENIA
author_facet CALVO,VICTOR
CORTÉS,PIEDAD
MORENO,YANKO
VEGA,ANDRES
SPODINE,EVGENIA
author_sort CALVO,VICTOR
title INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
title_short INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
title_full INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
title_fullStr INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
title_full_unstemmed INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
title_sort influence of hydrogen bridges on the magnetic properties of copper(ii) bis(trifluoroacetate) complexes
publisher Sociedad Chilena de Química
publishDate 2000
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200013
work_keys_str_mv AT calvovictor influenceofhydrogenbridgesonthemagneticpropertiesofcopperiibistrifluoroacetatecomplexes
AT cortespiedad influenceofhydrogenbridgesonthemagneticpropertiesofcopperiibistrifluoroacetatecomplexes
AT morenoyanko influenceofhydrogenbridgesonthemagneticpropertiesofcopperiibistrifluoroacetatecomplexes
AT vegaandres influenceofhydrogenbridgesonthemagneticpropertiesofcopperiibistrifluoroacetatecomplexes
AT spodineevgenia influenceofhydrogenbridgesonthemagneticpropertiesofcopperiibistrifluoroacetatecomplexes
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