INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES
Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a...
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Sociedad Chilena de Química
2000
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oai:scielo:S0366-164420000002000132000-08-25INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXESCALVO,VICTORCORTÉS,PIEDADMORENO,YANKOVEGA,ANDRESSPODINE,EVGENIA Hydrogen bonding magnetic exchange copper(II) trifluoroacetate Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a = 6.067(1)Å, b = 12.153(3)Å, c = 15.057(3)Å, <FONT FACE=Symbol>a</FONT>= 100.09(2), <FONT FACE=Symbol>b</FONT>= 99.15(2), <FONT FACE=Symbol>g</FONT>= 101.00(2) and Z = 2. The single crystal EPR spectrum of (1) shows to signals (ginfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.2 20002000-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200013en10.4067/S0366-16442000000200013 |
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Scielo Chile |
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Scielo Chile |
language |
English |
topic |
Hydrogen bonding magnetic exchange copper(II) trifluoroacetate |
spellingShingle |
Hydrogen bonding magnetic exchange copper(II) trifluoroacetate CALVO,VICTOR CORTÉS,PIEDAD MORENO,YANKO VEGA,ANDRES SPODINE,EVGENIA INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
description |
Copper(II) trifluoroacetate with three coordinated water molecules and two dioxane molecules (1) crystallized as a linear chain surrounded by a net of hydrogen bonds to the dioxane and trifluoroacetate. This complex [Cu(H2O)3(OOC-CF3) 2]·2(C4H8O 2) crystallizes in the triclinic space group P1 with a = 6.067(1)Å, b = 12.153(3)Å, c = 15.057(3)Å, <FONT FACE=Symbol>a</FONT>= 100.09(2), <FONT FACE=Symbol>b</FONT>= 99.15(2), <FONT FACE=Symbol>g</FONT>= 101.00(2) and Z = 2. The single crystal EPR spectrum of (1) shows to signals (g |
author |
CALVO,VICTOR CORTÉS,PIEDAD MORENO,YANKO VEGA,ANDRES SPODINE,EVGENIA |
author_facet |
CALVO,VICTOR CORTÉS,PIEDAD MORENO,YANKO VEGA,ANDRES SPODINE,EVGENIA |
author_sort |
CALVO,VICTOR |
title |
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
title_short |
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
title_full |
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
title_fullStr |
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
title_full_unstemmed |
INFLUENCE OF HYDROGEN BRIDGES ON THE MAGNETIC PROPERTIES OF COPPER(II) BIS(TRIFLUOROACETATE) COMPLEXES |
title_sort |
influence of hydrogen bridges on the magnetic properties of copper(ii) bis(trifluoroacetate) complexes |
publisher |
Sociedad Chilena de Química |
publishDate |
2000 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200013 |
work_keys_str_mv |
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_version_ |
1718438109677355008 |