Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine)
ABSTRACT 	Kinetic studies of the water gas shift reaction have been carried Æt in the presence of [Rh(COD)(4-picoline)2]P F6, (COD = 1,5-cyclooctadiene) as catalyst, immobilized on poly(4-vinylpyridine) 2% cross linked with divinylbenzene in contact with a mixture of 80% aqueous 2-ethoxyethan...
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Sociedad Chilena de Química
2000
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oai:scielo:S0366-164420000003000032001-03-23Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine)Pardey,A. J.Fernández,M.Alvarez,J.Ortega,M. C.Canestrari,M.Longo,C.Aguirre,P.Moya,S. A.Lujano,E.Baricelli,P. J. Water gas shift reaction rhodium poly(4-vinylpyridine ABSTRACT 	Kinetic studies of the water gas shift reaction have been carried Æt in the presence of [Rh(COD)(4-picoline)2]P F6, (COD = 1,5-cyclooctadiene) as catalyst, immobilized on poly(4-vinylpyridine) 2% cross linked with divinylbenzene in contact with a mixture of 80% aqueous 2-ethoxyethanol. The rhodium complex was anchored to the pyridine groups of the organic polymer. Analyses of kinetic results show a first order dependence on carbon monoxide pressure, a nonlinear dependence on rhodium total concentration and a segmented Arrhenius plot. These data are discussed in terms of a possible mechanism.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.3 20002000-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300003en10.4067/S0366-16442000000300003 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
Water gas shift reaction rhodium poly(4-vinylpyridine |
| spellingShingle |
Water gas shift reaction rhodium poly(4-vinylpyridine Pardey,A. J. Fernández,M. Alvarez,J. Ortega,M. C. Canestrari,M. Longo,C. Aguirre,P. Moya,S. A. Lujano,E. Baricelli,P. J. Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| description |
ABSTRACT 	Kinetic studies of the water gas shift reaction have been carried Æt in the presence of [Rh(COD)(4-picoline)2]P F6, (COD = 1,5-cyclooctadiene) as catalyst, immobilized on poly(4-vinylpyridine) 2% cross linked with divinylbenzene in contact with a mixture of 80% aqueous 2-ethoxyethanol. The rhodium complex was anchored to the pyridine groups of the organic polymer. Analyses of kinetic results show a first order dependence on carbon monoxide pressure, a nonlinear dependence on rhodium total concentration and a segmented Arrhenius plot. These data are discussed in terms of a possible mechanism. |
| author |
Pardey,A. J. Fernández,M. Alvarez,J. Ortega,M. C. Canestrari,M. Longo,C. Aguirre,P. Moya,S. A. Lujano,E. Baricelli,P. J. |
| author_facet |
Pardey,A. J. Fernández,M. Alvarez,J. Ortega,M. C. Canestrari,M. Longo,C. Aguirre,P. Moya,S. A. Lujano,E. Baricelli,P. J. |
| author_sort |
Pardey,A. J. |
| title |
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| title_short |
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| title_full |
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| title_fullStr |
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| title_full_unstemmed |
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) |
| title_sort |
kinetics of the water gas shift reaction catalyzed by [rh(cod)(4-picoline)2]pf6 immobilized on poly(4-vinylpyridine) |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2000 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300003 |
| work_keys_str_mv |
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| _version_ |
1718438112462372864 |