CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO
Ru(1%)/Support (SiO2 y Al2O3) were prepared by sol-gel processing, using H2O/Alcoxide molar ration and gelation pH different. The surface area increase, with the gelation acidity decrease. The TPR has shown metal-support interaction and reducibility degree different. In all catalysts the metallic di...
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Sociedad Chilena de Química
2000
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oai:scielo:S0366-164420000003000052001-03-23CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENOOrellana,FresiaPlaza de los Reyes,JorgeUrizar,Silvio sol-gel xerogel catalysis alumina, silice ruthenium Ru(1%)/Support (SiO2 y Al2O3) were prepared by sol-gel processing, using H2O/Alcoxide molar ration and gelation pH different. The surface area increase, with the gelation acidity decrease. The TPR has shown metal-support interaction and reducibility degree different. In all catalysts the metallic dispersion is low and the size of metallic ruthenium mainly depends of gelation pH. The activity the catalysts are probed in toluene hydrogenation. The principal product was methylcyclohexane, which increased with the metal particle size.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.3 20002000-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300005en10.4067/S0366-16442000000300005 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
sol-gel xerogel catalysis alumina, silice ruthenium |
spellingShingle |
sol-gel xerogel catalysis alumina, silice ruthenium Orellana,Fresia Plaza de los Reyes,Jorge Urizar,Silvio CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
description |
Ru(1%)/Support (SiO2 y Al2O3) were prepared by sol-gel processing, using H2O/Alcoxide molar ration and gelation pH different. The surface area increase, with the gelation acidity decrease. The TPR has shown metal-support interaction and reducibility degree different. In all catalysts the metallic dispersion is low and the size of metallic ruthenium mainly depends of gelation pH. The activity the catalysts are probed in toluene hydrogenation. The principal product was methylcyclohexane, which increased with the metal particle size. |
author |
Orellana,Fresia Plaza de los Reyes,Jorge Urizar,Silvio |
author_facet |
Orellana,Fresia Plaza de los Reyes,Jorge Urizar,Silvio |
author_sort |
Orellana,Fresia |
title |
CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
title_short |
CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
title_full |
CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
title_fullStr |
CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
title_full_unstemmed |
CATALIZADORES Ru/SiO2 y Ru/Al2O3 PREPARADOS POR SOL-GEL PARA HIDROGENACION DE TOLUENO |
title_sort |
catalizadores ru/sio2 y ru/al2o3 preparados por sol-gel para hidrogenacion de tolueno |
publisher |
Sociedad Chilena de Química |
publishDate |
2000 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300005 |
work_keys_str_mv |
AT orellanafresia catalizadoresrusio2yrual2o3preparadosporsolgelparahidrogenaciondetolueno AT plazadelosreyesjorge catalizadoresrusio2yrual2o3preparadosporsolgelparahidrogenaciondetolueno AT urizarsilvio catalizadoresrusio2yrual2o3preparadosporsolgelparahidrogenaciondetolueno |
_version_ |
1718438112998195200 |