HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES

In the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carr...

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Autores principales:	BARICELLI,P.J., LUJANO,R.E., MEDINA,L., LONGO,C., PARDEY,A.J., PASTENE,R., MOYA,S.A.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2000
Materias:	hydroformylation formaldehyde rhodium complexes methyl formate
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008
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spelling	oai:scielo:S0366-164420000003000082001-03-23HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXESBARICELLI,P.J.LUJANO,R.E.MEDINA,L.LONGO,C.PARDEY,A.J.PASTENE,R.MOYA,S.A. hydroformylation formaldehyde rhodium complexes methyl formate In the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carried out in an autoclave (Parr, 100 mL), 10 atm, CO/H2 = 1 and ratio catalyst/substrate 1/100. Preliminary kinetics parameters show a high catalytic activity of these complexes to the formation of methanol and methyl formateinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.3 20002000-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008en10.4067/S0366-16442000000300008
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	hydroformylation formaldehyde rhodium complexes methyl formate
spellingShingle	hydroformylation formaldehyde rhodium complexes methyl formate BARICELLI,P.J. LUJANO,R.E. MEDINA,L. LONGO,C. PARDEY,A.J. PASTENE,R. MOYA,S.A. HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
description	In the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carried out in an autoclave (Parr, 100 mL), 10 atm, CO/H2 = 1 and ratio catalyst/substrate 1/100. Preliminary kinetics parameters show a high catalytic activity of these complexes to the formation of methanol and methyl formate
author	BARICELLI,P.J. LUJANO,R.E. MEDINA,L. LONGO,C. PARDEY,A.J. PASTENE,R. MOYA,S.A.
author_facet	BARICELLI,P.J. LUJANO,R.E. MEDINA,L. LONGO,C. PARDEY,A.J. PASTENE,R. MOYA,S.A.
author_sort	BARICELLI,P.J.
title	HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
title_short	HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
title_full	HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
title_fullStr	HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
title_full_unstemmed	HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
title_sort	homogeneous catalysis reaction of formaldehyde with synthesis gas using rhodium complexes
publisher	Sociedad Chilena de Química
publishDate	2000
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008
work_keys_str_mv	AT baricellipj homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT lujanore homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT medinal homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT longoc homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT pardeyaj homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT pastener homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes AT moyasa homogeneouscatalysisreactionofformaldehydewithsynthesisgasusingrhodiumcomplexes
_version_	1718438113660895232

HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES

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