Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity

Kinetic and thermodynamic properties of the products of the intercalation of lithium in layered transition metal oxides and sulfides are strongly determined by lithium coordinative environment. Thus, the electrode potentials as well as the activation energies for lithium diffusion are higher in MoO3...

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Autores principales:	Santa Ana,M.A., Benavente,E., Páeza,J., Gonzáleza,G.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2000
Materias:	Lithium intercalation compounds molybdenum trioxide molybdenum disulfide nanocomposites lithium diffusivity
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300021
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spelling	oai:scielo:S0366-164420000003000212001-03-23Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium DiffusivitySanta Ana,M.A.Benavente,E.Páeza,J.Gonzáleza,G. Lithium intercalation compounds molybdenum trioxide molybdenum disulfide nanocomposites lithium diffusivity Kinetic and thermodynamic properties of the products of the intercalation of lithium in layered transition metal oxides and sulfides are strongly determined by lithium coordinative environment. Thus, the electrode potentials as well as the activation energies for lithium diffusion are higher in MoO3 than in MoS2. A similar effect is appreciated for the products of the co-intercalation of lithium and poly(ethylene oxide) into MoS2. The effect of lithium coordinative environment on these properties may be understood by analyzing a theoretical model considering host-guest back-donation charge transfer achieved by the local polarization of the lithium ligands in the interlaminar spacesinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.45 n.3 20002000-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300021en10.4067/S0366-16442000000300021
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Lithium intercalation compounds molybdenum trioxide molybdenum disulfide nanocomposites lithium diffusivity
spellingShingle	Lithium intercalation compounds molybdenum trioxide molybdenum disulfide nanocomposites lithium diffusivity Santa Ana,M.A. Benavente,E. Páeza,J. Gonzáleza,G. Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
description	Kinetic and thermodynamic properties of the products of the intercalation of lithium in layered transition metal oxides and sulfides are strongly determined by lithium coordinative environment. Thus, the electrode potentials as well as the activation energies for lithium diffusion are higher in MoO3 than in MoS2. A similar effect is appreciated for the products of the co-intercalation of lithium and poly(ethylene oxide) into MoS2. The effect of lithium coordinative environment on these properties may be understood by analyzing a theoretical model considering host-guest back-donation charge transfer achieved by the local polarization of the lithium ligands in the interlaminar spaces
author	Santa Ana,M.A. Benavente,E. Páeza,J. Gonzáleza,G.
author_facet	Santa Ana,M.A. Benavente,E. Páeza,J. Gonzáleza,G.
author_sort	Santa Ana,M.A.
title	Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
title_short	Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
title_full	Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
title_fullStr	Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
title_full_unstemmed	Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity
title_sort	intercalation of lithium and donor species in layered transition metal oxides and sulfides.: environment effects on lithium diffusivity
publisher	Sociedad Chilena de Química
publishDate	2000
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300021
work_keys_str_mv	AT santaanama intercalationoflithiumanddonorspeciesinlayeredtransitionmetaloxidesandsulfidesenvironmenteffectsonlithiumdiffusivity AT benaventee intercalationoflithiumanddonorspeciesinlayeredtransitionmetaloxidesandsulfidesenvironmenteffectsonlithiumdiffusivity AT paezaj intercalationoflithiumanddonorspeciesinlayeredtransitionmetaloxidesandsulfidesenvironmenteffectsonlithiumdiffusivity AT gonzalezag intercalationoflithiumanddonorspeciesinlayeredtransitionmetaloxidesandsulfidesenvironmenteffectsonlithiumdiffusivity
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Intercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity

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