Synthesis and Characterization of New Ruthenium Complexes With 11-carboxy-dipyrido (3,2-a:2,3-c)phenazine as Ligand
A general method for the synthesis of Ruthenium(II) complexes of the type [(HOOC-dppz)2RuX2] and [(HOOC-dppz)RuL2](PF6)2 (X = Cl- or SCN-, L = 2,2'-dipyridine or 4,4'-dimethyl-2,2'-dipyridine and HOOC-dppz = 11-carboxy-dipyrido(3,2-a:2',3'-c)phenazine), is reported. The comp...
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| Autores principales: | , , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2000
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000400010 |
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| Sumario: | A general method for the synthesis of Ruthenium(II) complexes of the type [(HOOC-dppz)2RuX2] and [(HOOC-dppz)RuL2](PF6)2 (X = Cl- or SCN-, L = 2,2'-dipyridine or 4,4'-dimethyl-2,2'-dipyridine and HOOC-dppz = 11-carboxy-dipyrido(3,2-a:2',3'-c)phenazine), is reported. The complexes were characterized by conventional technics as UV-Visible, IR and 1H-NMR spectroscopies and cyclic voltammetry. |
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