CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM

This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexano...

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Autores principales:	Castillo,A., Baricelli,P.J., Pardey,A.J., Moya,S.A.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2001
Materias:	1-Hexene copper catalyst oxidation reaction
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002
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spelling	oai:scielo:S0366-164420010001000022001-05-30CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEMCastillo,A.Baricelli,P.J.Pardey,A.J.Moya,S.A. 1-Hexene copper catalyst oxidation reaction This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºCinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.46 n.1 20012001-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002en10.4067/S0366-16442001000100002
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	1-Hexene copper catalyst oxidation reaction
spellingShingle	1-Hexene copper catalyst oxidation reaction Castillo,A. Baricelli,P.J. Pardey,A.J. Moya,S.A. CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
description	This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºC
author	Castillo,A. Baricelli,P.J. Pardey,A.J. Moya,S.A.
author_facet	Castillo,A. Baricelli,P.J. Pardey,A.J. Moya,S.A.
author_sort	Castillo,A.
title	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
title_short	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
title_full	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
title_fullStr	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
title_full_unstemmed	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
title_sort	catalitic oxidation of 1-hexene with molecular oxygen by the cu(ch3cn)2(no2)2/pd(ch3cn)2cl2 bimetallic system
publisher	Sociedad Chilena de Química
publishDate	2001
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002
work_keys_str_mv	AT castilloa cataliticoxidationof1hexenewithmolecularoxygenbythecuch3cn2no22pdch3cn2cl2bimetallicsystem AT baricellipj cataliticoxidationof1hexenewithmolecularoxygenbythecuch3cn2no22pdch3cn2cl2bimetallicsystem AT pardeyaj cataliticoxidationof1hexenewithmolecularoxygenbythecuch3cn2no22pdch3cn2cl2bimetallicsystem AT moyasa cataliticoxidationof1hexenewithmolecularoxygenbythecuch3cn2no22pdch3cn2cl2bimetallicsystem
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CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM

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