EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES
In the series of organometallic complexes N3P2(X)5P-SPACER-MLn X= Cl and OR, MLn= organometallic fragment , the delta31 P-NMR coordination chemical shift parameter correlates with the length of the spacer, decaying exponentially with the length of it. The bridging spacers behave like a "molecul...
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Autores principales: | DIAZ,CARLOS, MENDIZABAL,FERNANDO |
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Lenguaje: | English |
Publicado: |
Sociedad Chilena de Química
2001
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Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000300009 |
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