LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES

We have studied the lithium insertion into LiM2O4 (M = Mn, Fe, Co) using n-BuLi and electrochemical techniques. The oxides crystallized in the pure spinel phase S.G. Oh7(Fd3m). Probable cationic distributions were proposed based on XRD, Mössbauer and pzc measurements. The results demonstrate that an...

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Autores principales:	GAUTIER,JUAN LUIS, AHUMADA,ROXANA, MEZA,ERIKA, POILLERAT,GERARD
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2001
Materias:	Lithium insertion lithium cobalt oxide lithium manganese oxide lithium iron oxide spinels lithium batteries
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000300016
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spelling	oai:scielo:S0366-164420010003000162002-02-05LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDESGAUTIER,JUAN LUISAHUMADA,ROXANAMEZA,ERIKAPOILLERAT,GERARD Lithium insertion lithium cobalt oxide lithium manganese oxide lithium iron oxide spinels lithium batteries We have studied the lithium insertion into LiM2O4 (M = Mn, Fe, Co) using n-BuLi and electrochemical techniques. The oxides crystallized in the pure spinel phase S.G. Oh7(Fd3m). Probable cationic distributions were proposed based on XRD, Mössbauer and pzc measurements. The results demonstrate that an important factor in the extent of the lithium insertion reaction in mixed oxides is the presence of the highest oxidation state in the transition metal cations that are located in B-sites of the spinel frameworkinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.46 n.3 20012001-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000300016en10.4067/S0366-16442001000300016
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Lithium insertion lithium cobalt oxide lithium manganese oxide lithium iron oxide spinels lithium batteries
spellingShingle	Lithium insertion lithium cobalt oxide lithium manganese oxide lithium iron oxide spinels lithium batteries GAUTIER,JUAN LUIS AHUMADA,ROXANA MEZA,ERIKA POILLERAT,GERARD LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
description	We have studied the lithium insertion into LiM2O4 (M = Mn, Fe, Co) using n-BuLi and electrochemical techniques. The oxides crystallized in the pure spinel phase S.G. Oh7(Fd3m). Probable cationic distributions were proposed based on XRD, Mössbauer and pzc measurements. The results demonstrate that an important factor in the extent of the lithium insertion reaction in mixed oxides is the presence of the highest oxidation state in the transition metal cations that are located in B-sites of the spinel framework
author	GAUTIER,JUAN LUIS AHUMADA,ROXANA MEZA,ERIKA POILLERAT,GERARD
author_facet	GAUTIER,JUAN LUIS AHUMADA,ROXANA MEZA,ERIKA POILLERAT,GERARD
author_sort	GAUTIER,JUAN LUIS
title	LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
title_short	LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
title_full	LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
title_fullStr	LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
title_full_unstemmed	LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES
title_sort	lithium insertion into li-mn, li-fe and li-co oxides
publisher	Sociedad Chilena de Química
publishDate	2001
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000300016
work_keys_str_mv	AT gautierjuanluis lithiuminsertionintolimnlifeandlicooxides AT ahumadaroxana lithiuminsertionintolimnlifeandlicooxides AT mezaerika lithiuminsertionintolimnlifeandlicooxides AT poilleratgerard lithiuminsertionintolimnlifeandlicooxides
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LITHIUM INSERTION INTO Li-Mn, Li-Fe AND Li-Co OXIDES

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