FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalli...

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Autores principales:	Manzur,Carolina, Fuentealba,Mauricio, Carrillo,David, Boys,Daphne, Hamon,Jean-René
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2001
Materias:	hydrazone iron mixed sandwich ferrocene homobimetallic hydrazone organometallic hydrazone crystal structure
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004
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spelling	oai:scielo:S0366-164420010004000042002-09-05FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6Manzur,CarolinaFuentealba,MauricioCarrillo,DavidBoys,DaphneHamon,Jean-René hydrazone iron mixed sandwich ferrocene homobimetallic hydrazone organometallic hydrazone crystal structure The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalline and molecular structure has been determined and consists of two iron(II) sandwiches of the type [(h 5-Cp)Fe(h 6-arene)]+ and [(h 5-C5H4)Fe(h 5-Cp)], in anti position one with respect to the other, and linked by a zigzag hydrazonic spacerinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.46 n.4 20012001-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004en10.4067/S0366-16442001000400004
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	hydrazone iron mixed sandwich ferrocene homobimetallic hydrazone organometallic hydrazone crystal structure
spellingShingle	hydrazone iron mixed sandwich ferrocene homobimetallic hydrazone organometallic hydrazone crystal structure Manzur,Carolina Fuentealba,Mauricio Carrillo,David Boys,Daphne Hamon,Jean-René FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
description	The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalline and molecular structure has been determined and consists of two iron(II) sandwiches of the type [(h 5-Cp)Fe(h 6-arene)]+ and [(h 5-C5H4)Fe(h 5-Cp)], in anti position one with respect to the other, and linked by a zigzag hydrazonic spacer
author	Manzur,Carolina Fuentealba,Mauricio Carrillo,David Boys,Daphne Hamon,Jean-René
author_facet	Manzur,Carolina Fuentealba,Mauricio Carrillo,David Boys,Daphne Hamon,Jean-René
author_sort	Manzur,Carolina
title	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
title_short	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
title_full	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
title_fullStr	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
title_full_unstemmed	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6
title_sort	first x-ray crystal structure of a bimetallic complex containing a p -coordinated hydrazone: [(h 5-cp)fe(h 6-p-meoc6h4)-nhn=ch-(h 5-c5h4)fe(h 5-cp)]+pf6
publisher	Sociedad Chilena de Química
publishDate	2001
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004
work_keys_str_mv	AT manzurcarolina firstxraycrystalstructureofabimetalliccomplexcontainingapcoordinatedhydrazoneh5cpfeh6pmeoc6h4nhnchh5c5h4feh5cppf6 AT fuentealbamauricio firstxraycrystalstructureofabimetalliccomplexcontainingapcoordinatedhydrazoneh5cpfeh6pmeoc6h4nhnchh5c5h4feh5cppf6 AT carrillodavid firstxraycrystalstructureofabimetalliccomplexcontainingapcoordinatedhydrazoneh5cpfeh6pmeoc6h4nhnchh5c5h4feh5cppf6 AT boysdaphne firstxraycrystalstructureofabimetalliccomplexcontainingapcoordinatedhydrazoneh5cpfeh6pmeoc6h4nhnchh5c5h4feh5cppf6 AT hamonjeanrene firstxraycrystalstructureofabimetalliccomplexcontainingapcoordinatedhydrazoneh5cpfeh6pmeoc6h4nhnchh5c5h4feh5cppf6
_version_	1718438136669798400

FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

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