FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalli...

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Autores principales: Manzur,Carolina, Fuentealba,Mauricio, Carrillo,David, Boys,Daphne, Hamon,Jean-René
Lenguaje:English
Publicado: Sociedad Chilena de Química 2001
Materias:
hydrazone
iron mixed sandwich
ferrocene
homobimetallic hydrazone
organometallic hydrazone
crystal structure
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004
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