POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE

From the diphenol N-(2,6-diiodo-4-nitrophenyl)-3,3-bis(4-hydroxyphenyl)-butanamide, the synthesis of the poly(carbonate) with phosgene, the poly(thiocarbonate) with thiophosgene and the poly(ester)s with adipoyl chloride, isophthaloyl chloride and terephthaloyl chloride are described under phase tra...

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Autores principales:	Tagle,L.H., Diaz,F.R., Vivanco,A.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2002
Materias:	diphenol-amide poly(carbonate) poly(thiocarbonate) poly(ester)s phase transfer catalysis
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000200014
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spelling	oai:scielo:S0366-164420020002000142002-10-14POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDETagle,L.H.Diaz,F.R.Vivanco,A. diphenol-amide poly(carbonate) poly(thiocarbonate) poly(ester)s phase transfer catalysis From the diphenol N-(2,6-diiodo-4-nitrophenyl)-3,3-bis(4-hydroxyphenyl)-butanamide, the synthesis of the poly(carbonate) with phosgene, the poly(thiocarbonate) with thiophosgene and the poly(ester)s with adipoyl chloride, isophthaloyl chloride and terephthaloyl chloride are described under phase transfer conditions using several quaternary ammonium salts as catalysts. The bahaviour of the catalysts was evaluated by the yields and the inherent viscosity values, comparing them with those obtained without catalyst. In general the phase transfer process was effective in all cases observing an increase of both parameters. All the polymers were insoluble in the reaction media which limited the growth of the polymeric chainsinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.2 20022002-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000200014en10.4067/S0366-16442002000200014
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	diphenol-amide poly(carbonate) poly(thiocarbonate) poly(ester)s phase transfer catalysis
spellingShingle	diphenol-amide poly(carbonate) poly(thiocarbonate) poly(ester)s phase transfer catalysis Tagle,L.H. Diaz,F.R. Vivanco,A. POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
description	From the diphenol N-(2,6-diiodo-4-nitrophenyl)-3,3-bis(4-hydroxyphenyl)-butanamide, the synthesis of the poly(carbonate) with phosgene, the poly(thiocarbonate) with thiophosgene and the poly(ester)s with adipoyl chloride, isophthaloyl chloride and terephthaloyl chloride are described under phase transfer conditions using several quaternary ammonium salts as catalysts. The bahaviour of the catalysts was evaluated by the yields and the inherent viscosity values, comparing them with those obtained without catalyst. In general the phase transfer process was effective in all cases observing an increase of both parameters. All the polymers were insoluble in the reaction media which limited the growth of the polymeric chains
author	Tagle,L.H. Diaz,F.R. Vivanco,A.
author_facet	Tagle,L.H. Diaz,F.R. Vivanco,A.
author_sort	Tagle,L.H.
title	POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
title_short	POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
title_full	POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
title_fullStr	POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
title_full_unstemmed	POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE
title_sort	polymerization by phase transfer catalysis. 28. condensation polymers derived from a diiodine diphenol-amide
publisher	Sociedad Chilena de Química
publishDate	2002
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000200014
work_keys_str_mv	AT taglelh polymerizationbyphasetransfercatalysis28condensationpolymersderivedfromadiiodinediphenolamide AT diazfr polymerizationbyphasetransfercatalysis28condensationpolymersderivedfromadiiodinediphenolamide AT vivancoa polymerizationbyphasetransfercatalysis28condensationpolymersderivedfromadiiodinediphenolamide
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POLYMERIZATION BY PHASE TRANSFER CATALYSIS. 28. CONDENSATION POLYMERS DERIVED FROM A DIIODINE DIPHENOL-AMIDE

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