RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION

Reaction of the dinuclear complex [{(eta5-C5Me5)RhCl} 2(µ-Cl)2] with the chiral phosphine (R)-Ph2PCH2CHMeCH2 OH leads to the complex [{(eta5-C5Me5)RhCl 2(eta¹-Ph2PCH2 CHMeCH2OH-P)](1). This reaction, in the presence of AgBF4, yields the cationic compound [{(eta5-C5Me5)RhCl(eta²- Ph2PCH2CHMeCH2OH-P,O...

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Autores principales:	SANHUEZA,JULIO, CONTRERAS,RAUL, VALDERRAMA,MAURICIO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2002
Materias:	Rhodium ruthenium chiral bidentate ligand chiral phosphine chiral-at-metal complexes
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000300005
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spelling	oai:scielo:S0366-164420020003000052014-08-20RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATIONSANHUEZA,JULIOCONTRERAS,RAULVALDERRAMA,MAURICIO Rhodium ruthenium chiral bidentate ligand chiral phosphine chiral-at-metal complexes Reaction of the dinuclear complex [{(eta5-C5Me5)RhCl} 2(µ-Cl)2] with the chiral phosphine (R)-Ph2PCH2CHMeCH2 OH leads to the complex [{(eta5-C5Me5)RhCl 2(eta¹-Ph2PCH2 CHMeCH2OH-P)](1). This reaction, in the presence of AgBF4, yields the cationic compound [{(eta5-C5Me5)RhCl(eta²- Ph2PCH2CHMeCH2OH-P,O)]BF 4(2). Variable-temperature ¹H NMR and circular dichroism experiments support the stereoselective eta²-chelate coordination of the ligand and the proposed configuration for the metal centre. In a similar way, the reaction of the dimer [{(eta6-C6Me6)RuCl} 2(µ-Cl)2] with the ligands (R)- and (S)-Ph2PCH2CHMeCH2 OH afford the neutral complexes [(eta6-C6Me6)RuCl 2{eta¹-PPh2CH2 CHMeCH2OH-P}] [R-ligand (3), S-ligand (4)], which in turn react with AgBF4 to give the cationic compounds [(eta6-C6Me6)RuCl{eta²-PPh2CH2CHMeCH2 OH-P,O}]BF4 [R-ligand (5), S-ligand (6)]. All complexes have been characterised by elemental analysis, IR and multinuclear NMR spectroscopiesinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.3 20022002-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000300005en10.4067/S0366-16442002000300005
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Rhodium ruthenium chiral bidentate ligand chiral phosphine chiral-at-metal complexes
spellingShingle	Rhodium ruthenium chiral bidentate ligand chiral phosphine chiral-at-metal complexes SANHUEZA,JULIO CONTRERAS,RAUL VALDERRAMA,MAURICIO RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
description	Reaction of the dinuclear complex [{(eta5-C5Me5)RhCl} 2(µ-Cl)2] with the chiral phosphine (R)-Ph2PCH2CHMeCH2 OH leads to the complex [{(eta5-C5Me5)RhCl 2(eta¹-Ph2PCH2 CHMeCH2OH-P)](1). This reaction, in the presence of AgBF4, yields the cationic compound [{(eta5-C5Me5)RhCl(eta²- Ph2PCH2CHMeCH2OH-P,O)]BF 4(2). Variable-temperature ¹H NMR and circular dichroism experiments support the stereoselective eta²-chelate coordination of the ligand and the proposed configuration for the metal centre. In a similar way, the reaction of the dimer [{(eta6-C6Me6)RuCl} 2(µ-Cl)2] with the ligands (R)- and (S)-Ph2PCH2CHMeCH2 OH afford the neutral complexes [(eta6-C6Me6)RuCl 2{eta¹-PPh2CH2 CHMeCH2OH-P}] [R-ligand (3), S-ligand (4)], which in turn react with AgBF4 to give the cationic compounds [(eta6-C6Me6)RuCl{eta²-PPh2CH2CHMeCH2 OH-P,O}]BF4 [R-ligand (5), S-ligand (6)]. All complexes have been characterised by elemental analysis, IR and multinuclear NMR spectroscopies
author	SANHUEZA,JULIO CONTRERAS,RAUL VALDERRAMA,MAURICIO
author_facet	SANHUEZA,JULIO CONTRERAS,RAUL VALDERRAMA,MAURICIO
author_sort	SANHUEZA,JULIO
title	RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
title_short	RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
title_full	RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
title_fullStr	RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
title_full_unstemmed	RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION
title_sort	rhodium(iii) and ruthenium(ii) complexes with the chiral phosphine-alcohol ph2pch2chmech2oh: synthesis and characterisation
publisher	Sociedad Chilena de Química
publishDate	2002
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000300005
work_keys_str_mv	AT sanhuezajulio rhodiumiiiandrutheniumiicomplexeswiththechiralphosphinealcoholph2pch2chmech2ohsynthesisandcharacterisation AT contrerasraul rhodiumiiiandrutheniumiicomplexeswiththechiralphosphinealcoholph2pch2chmech2ohsynthesisandcharacterisation AT valderramamauricio rhodiumiiiandrutheniumiicomplexeswiththechiralphosphinealcoholph2pch2chmech2ohsynthesisandcharacterisation
_version_	1718438147338010624

RHODIUM(III) AND RUTHENIUM(II) COMPLEXES WITH THE CHIRAL PHOSPHINE-ALCOHOL Ph2PCH2CHMeCH2OH: SYNTHESIS AND CHARACTERISATION

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