PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE

The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium pro...

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Autores principales: BECERRA,A., IRIARTE,M. E., DIMITRIJEWITS,M., CASTRO-LUNA,A.
Lenguaje:English
Publicado: Sociedad Chilena de Química 2002
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400010
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spelling oai:scielo:S0366-164420020004000102009-12-18PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANEBECERRA,A.IRIARTE,M. E.DIMITRIJEWITS,M.CASTRO-LUNA,A. Methane-Carbon dioxide reforming Rh-promoted Ni/alumina catalysts synthesis gas The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium promoted catalysts, which produced an increase in the catalytic activity for the reforming reaction. However, the specific activity measured by the turnover frequency resulted practically constant for promoted and not promoted catalysts suggesting that the increase in the number of metal surface atoms caused the activity enhancement.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.4 20022002-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400010en10.4067/S0366-16442002000400010
institution Scielo Chile
collection Scielo Chile
language English
topic Methane-Carbon dioxide reforming
Rh-promoted Ni/alumina catalysts
synthesis gas
spellingShingle Methane-Carbon dioxide reforming
Rh-promoted Ni/alumina catalysts
synthesis gas
BECERRA,A.
IRIARTE,M. E.
DIMITRIJEWITS,M.
CASTRO-LUNA,A.
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
description The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium promoted catalysts, which produced an increase in the catalytic activity for the reforming reaction. However, the specific activity measured by the turnover frequency resulted practically constant for promoted and not promoted catalysts suggesting that the increase in the number of metal surface atoms caused the activity enhancement.
author BECERRA,A.
IRIARTE,M. E.
DIMITRIJEWITS,M.
CASTRO-LUNA,A.
author_facet BECERRA,A.
IRIARTE,M. E.
DIMITRIJEWITS,M.
CASTRO-LUNA,A.
author_sort BECERRA,A.
title PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
title_short PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
title_full PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
title_fullStr PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
title_full_unstemmed PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
title_sort promoting effects of rhodium on supported nickel catalysts in the dry reforming of methane
publisher Sociedad Chilena de Química
publishDate 2002
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400010
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