PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE
The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium pro...
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Sociedad Chilena de Química
2002
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oai:scielo:S0366-164420020004000102009-12-18PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANEBECERRA,A.IRIARTE,M. E.DIMITRIJEWITS,M.CASTRO-LUNA,A. Methane-Carbon dioxide reforming Rh-promoted Ni/alumina catalysts synthesis gas The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium promoted catalysts, which produced an increase in the catalytic activity for the reforming reaction. However, the specific activity measured by the turnover frequency resulted practically constant for promoted and not promoted catalysts suggesting that the increase in the number of metal surface atoms caused the activity enhancement.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.4 20022002-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400010en10.4067/S0366-16442002000400010 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Methane-Carbon dioxide reforming Rh-promoted Ni/alumina catalysts synthesis gas |
spellingShingle |
Methane-Carbon dioxide reforming Rh-promoted Ni/alumina catalysts synthesis gas BECERRA,A. IRIARTE,M. E. DIMITRIJEWITS,M. CASTRO-LUNA,A. PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
description |
The effect of addition of rhodium upon the characteristics and catalytic activity in carbon dioxide reforming of methane using rhodium promoted nickel catalysts supported on two commercial alumina, was studied. The number of reduced metallic atoms exposed on the surface increased for the rhodium promoted catalysts, which produced an increase in the catalytic activity for the reforming reaction. However, the specific activity measured by the turnover frequency resulted practically constant for promoted and not promoted catalysts suggesting that the increase in the number of metal surface atoms caused the activity enhancement. |
author |
BECERRA,A. IRIARTE,M. E. DIMITRIJEWITS,M. CASTRO-LUNA,A. |
author_facet |
BECERRA,A. IRIARTE,M. E. DIMITRIJEWITS,M. CASTRO-LUNA,A. |
author_sort |
BECERRA,A. |
title |
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
title_short |
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
title_full |
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
title_fullStr |
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
title_full_unstemmed |
PROMOTING EFFECTS OF RHODIUM ON SUPPORTED NICKEL CATALYSTS IN THE DRY REFORMING OF METHANE |
title_sort |
promoting effects of rhodium on supported nickel catalysts in the dry reforming of methane |
publisher |
Sociedad Chilena de Química |
publishDate |
2002 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400010 |
work_keys_str_mv |
AT becerraa promotingeffectsofrhodiumonsupportednickelcatalystsinthedryreformingofmethane AT iriarteme promotingeffectsofrhodiumonsupportednickelcatalystsinthedryreformingofmethane AT dimitrijewitsm promotingeffectsofrhodiumonsupportednickelcatalystsinthedryreformingofmethane AT castrolunaa promotingeffectsofrhodiumonsupportednickelcatalystsinthedryreformingofmethane |
_version_ |
1718438151771389952 |