USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS

Irradiation of thin films of a polyketonate Pd/Ni heteronuclear complex, PdNi(DBA)2 [DBA = dibenzoylacetone)], produced uniform films containing Pd and Ni as shown by EDAX analysis. The X-ray powder diffraction spectrum showed peaks associated with elemental Pd and NiO. The morphology of the films w...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	BUONO-CORE,G.E., TEJOS,M., CABELLO,G., AROS,F., HILL,R.H.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2002
Materias:	thin films palladium nickel oxide photodeposition
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400021
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0366-16442002000400021
record_format	dspace
spelling	oai:scielo:S0366-164420020004000212009-12-18USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMSBUONO-CORE,G.E.TEJOS,M.CABELLO,G.AROS,F.HILL,R.H. thin films palladium nickel oxide photodeposition Irradiation of thin films of a polyketonate Pd/Ni heteronuclear complex, PdNi(DBA)2 [DBA = dibenzoylacetone)], produced uniform films containing Pd and Ni as shown by EDAX analysis. The X-ray powder diffraction spectrum showed peaks associated with elemental Pd and NiO. The morphology of the films was examined by SEM measurements showing a uniform granular surface with particle sizes of 100 nm or less. The XPS results show that the ratio of Pd/Ni (1:17) present in the film does reflect the stoichiometry in the starting complex. The large amount of carbon (52 %) detected on the surface of the film may be due to the presence of phenyl rings in the precursor complex.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.4 20022002-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400021en10.4067/S0366-16442002000400021
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	thin films palladium nickel oxide photodeposition
spellingShingle	thin films palladium nickel oxide photodeposition BUONO-CORE,G.E. TEJOS,M. CABELLO,G. AROS,F. HILL,R.H. USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
description	Irradiation of thin films of a polyketonate Pd/Ni heteronuclear complex, PdNi(DBA)2 [DBA = dibenzoylacetone)], produced uniform films containing Pd and Ni as shown by EDAX analysis. The X-ray powder diffraction spectrum showed peaks associated with elemental Pd and NiO. The morphology of the films was examined by SEM measurements showing a uniform granular surface with particle sizes of 100 nm or less. The XPS results show that the ratio of Pd/Ni (1:17) present in the film does reflect the stoichiometry in the starting complex. The large amount of carbon (52 %) detected on the surface of the film may be due to the presence of phenyl rings in the precursor complex.
author	BUONO-CORE,G.E. TEJOS,M. CABELLO,G. AROS,F. HILL,R.H.
author_facet	BUONO-CORE,G.E. TEJOS,M. CABELLO,G. AROS,F. HILL,R.H.
author_sort	BUONO-CORE,G.E.
title	USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
title_short	USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
title_full	USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
title_fullStr	USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
title_full_unstemmed	USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS
title_sort	use of a single-source mixed-metal precursor for the photodeposition of pd/ni oxides thin films
publisher	Sociedad Chilena de Química
publishDate	2002
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400021
work_keys_str_mv	AT buonocorege useofasinglesourcemixedmetalprecursorforthephotodepositionofpdnioxidesthinfilms AT tejosm useofasinglesourcemixedmetalprecursorforthephotodepositionofpdnioxidesthinfilms AT cabellog useofasinglesourcemixedmetalprecursorforthephotodepositionofpdnioxidesthinfilms AT arosf useofasinglesourcemixedmetalprecursorforthephotodepositionofpdnioxidesthinfilms AT hillrh useofasinglesourcemixedmetalprecursorforthephotodepositionofpdnioxidesthinfilms
_version_	1718438154192551936

USE OF A SINGLE-SOURCE MIXED-METAL PRECURSOR FOR THE PHOTODEPOSITION OF Pd/Ni OXIDES THIN FILMS

Ejemplares similares