Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media

The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to e...

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Autores principales: Cassani,Julia, Luna,Héctor, Navarro,Arturo, Castillo,Edmundo
Lenguaje:English
Publicado: Pontificia Universidad Católica de Valparaíso 2007
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400004
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spelling oai:scielo:S0717-345820070004000042009-01-19Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent mediaCassani,JuliaLuna,HéctorNavarro,ArturoCastillo,Edmundo CAL-B electronic effects esterification lipase phenylpropanoid acids The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to electronic effects, when compared to the unsaturated acids with the hydrogenated acids. It is also clear that in the saturated acids there still remain some unclear effects related to the aromatic substituents.info:eu-repo/semantics/openAccessPontificia Universidad Católica de ValparaísoElectronic Journal of Biotechnology v.10 n.4 20072007-10-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400004en10.4067/S0717-34582007000400004
institution Scielo Chile
collection Scielo Chile
language English
topic CAL-B
electronic effects
esterification
lipase
phenylpropanoid acids
spellingShingle CAL-B
electronic effects
esterification
lipase
phenylpropanoid acids
Cassani,Julia
Luna,Héctor
Navarro,Arturo
Castillo,Edmundo
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
description The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to electronic effects, when compared to the unsaturated acids with the hydrogenated acids. It is also clear that in the saturated acids there still remain some unclear effects related to the aromatic substituents.
author Cassani,Julia
Luna,Héctor
Navarro,Arturo
Castillo,Edmundo
author_facet Cassani,Julia
Luna,Héctor
Navarro,Arturo
Castillo,Edmundo
author_sort Cassani,Julia
title Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
title_short Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
title_full Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
title_fullStr Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
title_full_unstemmed Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
title_sort comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
publisher Pontificia Universidad Católica de Valparaíso
publishDate 2007
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400004
work_keys_str_mv AT cassanijulia comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia
AT lunahector comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia
AT navarroarturo comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia
AT castilloedmundo comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia
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