Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media
The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to e...
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Pontificia Universidad Católica de Valparaíso
2007
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oai:scielo:S0717-345820070004000042009-01-19Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent mediaCassani,JuliaLuna,HéctorNavarro,ArturoCastillo,Edmundo CAL-B electronic effects esterification lipase phenylpropanoid acids The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to electronic effects, when compared to the unsaturated acids with the hydrogenated acids. It is also clear that in the saturated acids there still remain some unclear effects related to the aromatic substituents.info:eu-repo/semantics/openAccessPontificia Universidad Católica de ValparaísoElectronic Journal of Biotechnology v.10 n.4 20072007-10-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400004en10.4067/S0717-34582007000400004 |
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Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
CAL-B electronic effects esterification lipase phenylpropanoid acids |
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CAL-B electronic effects esterification lipase phenylpropanoid acids Cassani,Julia Luna,Héctor Navarro,Arturo Castillo,Edmundo Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
description |
The esterification of phenylpropanoid and hydrophenylpropanoid acids, catalyzed by candida antarctica lipase B (CAL-B), with several alcohols has demonstrated that the substitution pattern on the aromatic ring has a very significant influence on the reactivity of the carboxyl group due, mainly, to electronic effects, when compared to the unsaturated acids with the hydrogenated acids. It is also clear that in the saturated acids there still remain some unclear effects related to the aromatic substituents. |
author |
Cassani,Julia Luna,Héctor Navarro,Arturo Castillo,Edmundo |
author_facet |
Cassani,Julia Luna,Héctor Navarro,Arturo Castillo,Edmundo |
author_sort |
Cassani,Julia |
title |
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
title_short |
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
title_full |
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
title_fullStr |
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
title_full_unstemmed |
Comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
title_sort |
comparative esterification of phenylpropanoids versus hydrophenylpropanoids acids catalyzed by lipase in organic solvent media |
publisher |
Pontificia Universidad Católica de Valparaíso |
publishDate |
2007 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400004 |
work_keys_str_mv |
AT cassanijulia comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia AT lunahector comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia AT navarroarturo comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia AT castilloedmundo comparativeesterificationofphenylpropanoidsversushydrophenylpropanoidsacidscatalyzedbylipaseinorganicsolventmedia |
_version_ |
1718441773921992704 |