SYNTHESIS AND CHARACTERIZATION OF MACROMONOMERS FROM OXAZOLINE DERIVATIVES

The macromonomers alpha - methyl-omega -[ N-(4-vinylbenzyl)piperazine]poly( N-methylethyleneimine), bis[2-(N-[4-vinylbenzylpiperazinyl])-2-butene-poly(N-methylenimine)] and alpha -(1-buten)-omega -[ N-piperidyl]poly( N-methylethylenimine) were obtained by ionic polymerization and subsequent function...

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Autores principales: POOLEY T,S. AMALIA, RIVAS,BERNABÉ L, SAN MARTÍN,CARLOS
Lenguaje:English
Publicado: Sociedad Chilena de Química 2003
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000100015
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Sumario:The macromonomers alpha - methyl-omega -[ N-(4-vinylbenzyl)piperazine]poly( N-methylethyleneimine), bis[2-(N-[4-vinylbenzylpiperazinyl])-2-butene-poly(N-methylenimine)] and alpha -(1-buten)-omega -[ N-piperidyl]poly( N-methylethylenimine) were obtained by ionic polymerization and subsequent functionalization. The yield of these macromonomers ranged between 40 and 85% These compounds were characterized by size exclusion chromatography (SEC), ¹H and 13C-NMR, and FT-IR spectroscopy