STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR
The modification of camphor at C(3) by an aldolization reaction using decanal followed by oxidation of the alcohols mixture was studied. The oxidation of the alcohols mixture with sodium hypochlorite in pure ethanoic acid produces only 3-a-chloro-3-exo-decanoyl-1,7,7-trimethyl bicyclo[2.2.1]heptan-2...
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Sociedad Chilena de Química
2003
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Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200007 |
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oai:scielo:S0717-970720030002000072004-01-29STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHORZárraga O.,MiguelMiranda M.,AlbertoThe modification of camphor at C(3) by an aldolization reaction using decanal followed by oxidation of the alcohols mixture was studied. The oxidation of the alcohols mixture with sodium hypochlorite in pure ethanoic acid produces only 3-a-chloro-3-exo-decanoyl-1,7,7-trimethyl bicyclo[2.2.1]heptan-2-oneinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.48 n.2 20032003-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200007en10.4067/S0717-97072003000200007 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
description |
The modification of camphor at C(3) by an aldolization reaction using decanal followed by oxidation of the alcohols mixture was studied. The oxidation of the alcohols mixture with sodium hypochlorite in pure ethanoic acid produces only 3-a-chloro-3-exo-decanoyl-1,7,7-trimethyl bicyclo[2.2.1]heptan-2-one |
author |
Zárraga O.,Miguel Miranda M.,Alberto |
spellingShingle |
Zárraga O.,Miguel Miranda M.,Alberto STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
author_facet |
Zárraga O.,Miguel Miranda M.,Alberto |
author_sort |
Zárraga O.,Miguel |
title |
STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
title_short |
STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
title_full |
STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
title_fullStr |
STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
title_full_unstemmed |
STEREOSELECTIVE SYNTHESIS OF 3-alpha-CHLORO-3-EXO-DECANOYL CAMPHOR |
title_sort |
stereoselective synthesis of 3-alpha-chloro-3-exo-decanoyl camphor |
publisher |
Sociedad Chilena de Química |
publishDate |
2003 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200007 |
work_keys_str_mv |
AT zarragaomiguel stereoselectivesynthesisof3alphachloro3exodecanoylcamphor AT mirandamalberto stereoselectivesynthesisof3alphachloro3exodecanoylcamphor |
_version_ |
1718445324430737408 |