OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND

The oxidation product of the binuclear copper (I) complex Cu2L(ClO4)2 (L = N,N'-bis-(6-methyl-2-pyridil) (2'-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, [Cu2L(Me-O)2](ClO4 )2, the metal centres are bridged by two methoxide gro...

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Autores principales:	Calero,Rolando, Vega,Andrés, García,Ana María, Spodin,Evgenia, Manzur,Jorge
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2003
Materias:	dimeric copper complexes oxidation catalysis
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200015
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spelling	oai:scielo:S0717-970720030002000152004-01-29OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGANDCalero,RolandoVega,AndrésGarcía,Ana MaríaSpodin,EvgeniaManzur,Jorge dimeric copper complexes oxidation catalysis The oxidation product of the binuclear copper (I) complex Cu2L(ClO4)2 (L = N,N'-bis-(6-methyl-2-pyridil) (2'-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, [Cu2L(Me-O)2](ClO4 )2, the metal centres are bridged by two methoxide groups, and the oxygenation of the xylyl spacer of the hexadentate ligand is not observed. The copper(I) complex was found to be a catalyst for the oxidation of 3,5-ditertbutylcatechol to 3,5-ditertbutyl-o-benzoquinone by molecular oxygeninfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.48 n.2 20032003-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200015en10.4067/S0717-97072003000200015
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	dimeric copper complexes oxidation catalysis
spellingShingle	dimeric copper complexes oxidation catalysis Calero,Rolando Vega,Andrés García,Ana María Spodin,Evgenia Manzur,Jorge OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
description	The oxidation product of the binuclear copper (I) complex Cu2L(ClO4)2 (L = N,N'-bis-(6-methyl-2-pyridil) (2'-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, [Cu2L(Me-O)2](ClO4 )2, the metal centres are bridged by two methoxide groups, and the oxygenation of the xylyl spacer of the hexadentate ligand is not observed. The copper(I) complex was found to be a catalyst for the oxidation of 3,5-ditertbutylcatechol to 3,5-ditertbutyl-o-benzoquinone by molecular oxygen
author	Calero,Rolando Vega,Andrés García,Ana María Spodin,Evgenia Manzur,Jorge
author_facet	Calero,Rolando Vega,Andrés García,Ana María Spodin,Evgenia Manzur,Jorge
author_sort	Calero,Rolando
title	OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
title_short	OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
title_full	OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
title_fullStr	OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
title_full_unstemmed	OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND
title_sort	oxidation and catalytic properties of a binuclear copper(i) complex with a meta-xylyl spacer ligand
publisher	Sociedad Chilena de Química
publishDate	2003
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200015
work_keys_str_mv	AT calerorolando oxidationandcatalyticpropertiesofabinuclearcoppericomplexwithametaxylylspacerligand AT vegaandres oxidationandcatalyticpropertiesofabinuclearcoppericomplexwithametaxylylspacerligand AT garciaanamaria oxidationandcatalyticpropertiesofabinuclearcoppericomplexwithametaxylylspacerligand AT spodinevgenia oxidationandcatalyticpropertiesofabinuclearcoppericomplexwithametaxylylspacerligand AT manzurjorge oxidationandcatalyticpropertiesofabinuclearcoppericomplexwithametaxylylspacerligand
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OXIDATION AND CATALYTIC PROPERTIES OF A BINUCLEAR COPPER(I) COMPLEX WITH A META-XYLYL SPACER LIGAND

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