THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE

Crystal and molecular structure and the thermal properties of (N,N-dibencyl)-4-nitrophenylsulfenamide, (C6H5CH2)2 NSC6H4-4-NO2, is herein presented. The structure is a divalent sulfur compound that crystallized in the monoclinic system, space group P2(1)/c with a=9.274(2), b=6.013(1), c=32.147(9) Å,...

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Autores principales:	Brito,Iván, Restovic,Ambrosio, Pedrero,Samuel, Mancilla,Arlett, Vargas,Danitza, León,Yasna, Ramirez,Eduardo, Arias,Mauricio, Brown,Kareen, Alvarez,Aldo, Arancibia,Alejandra, López-Rodriguez,Matías
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2003
Materias:	Sulfenamides sulfenic acid derivatives divalent sulfur compounds
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300010
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spelling	oai:scielo:S0717-970720030003000102004-01-30THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDEBrito,IvánRestovic,AmbrosioPedrero,SamuelMancilla,ArlettVargas,DanitzaLeón,YasnaRamirez,EduardoArias,MauricioBrown,KareenAlvarez,AldoArancibia,AlejandraLópez-Rodriguez,Matías Sulfenamides sulfenic acid derivatives divalent sulfur compounds Crystal and molecular structure and the thermal properties of (N,N-dibencyl)-4-nitrophenylsulfenamide, (C6H5CH2)2 NSC6H4-4-NO2, is herein presented. The structure is a divalent sulfur compound that crystallized in the monoclinic system, space group P2(1)/c with a=9.274(2), b=6.013(1), c=32.147(9) Å, b=95.55(2) and Dx=1.305 g cm-3 with Z=4. The plane C-S-N form a dihedral angle of 77.4(3) with the plane C19-N1-C20, and it represent a notable difference with other sulfenamides described in the literature. The thermogravimetric analysis reveal a decomposition of the product in two steps and another event, probably, associated to a endothermic phase transitioninfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.48 n.3 20032003-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300010en10.4067/S0717-97072003000300010
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Sulfenamides sulfenic acid derivatives divalent sulfur compounds
spellingShingle	Sulfenamides sulfenic acid derivatives divalent sulfur compounds Brito,Iván Restovic,Ambrosio Pedrero,Samuel Mancilla,Arlett Vargas,Danitza León,Yasna Ramirez,Eduardo Arias,Mauricio Brown,Kareen Alvarez,Aldo Arancibia,Alejandra López-Rodriguez,Matías THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
description	Crystal and molecular structure and the thermal properties of (N,N-dibencyl)-4-nitrophenylsulfenamide, (C6H5CH2)2 NSC6H4-4-NO2, is herein presented. The structure is a divalent sulfur compound that crystallized in the monoclinic system, space group P2(1)/c with a=9.274(2), b=6.013(1), c=32.147(9) Å, b=95.55(2) and Dx=1.305 g cm-3 with Z=4. The plane C-S-N form a dihedral angle of 77.4(3) with the plane C19-N1-C20, and it represent a notable difference with other sulfenamides described in the literature. The thermogravimetric analysis reveal a decomposition of the product in two steps and another event, probably, associated to a endothermic phase transition
author	Brito,Iván Restovic,Ambrosio Pedrero,Samuel Mancilla,Arlett Vargas,Danitza León,Yasna Ramirez,Eduardo Arias,Mauricio Brown,Kareen Alvarez,Aldo Arancibia,Alejandra López-Rodriguez,Matías
author_facet	Brito,Iván Restovic,Ambrosio Pedrero,Samuel Mancilla,Arlett Vargas,Danitza León,Yasna Ramirez,Eduardo Arias,Mauricio Brown,Kareen Alvarez,Aldo Arancibia,Alejandra López-Rodriguez,Matías
author_sort	Brito,Iván
title	THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
title_short	THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
title_full	THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
title_fullStr	THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
title_full_unstemmed	THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE
title_sort	thermal and x-ray crystallographic structural studies on (n,n-dibencyl)-4-nitrophenylsulfenamide
publisher	Sociedad Chilena de Química
publishDate	2003
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300010
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THERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE

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