ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING

ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING

Considering that electropolymerization process occurs via radical intermediates, it was used a stable nitroxide radical such as TEMPO, with the aim to stabilize the species generated in the electrode/solution interface. The obtained results show that TEMPO really acts as a "radical trapping&quo...

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Autores principales: del Valle,M. Angélica, Díaz,Fernando R., Bustos,Fabiola E., Guerra,Liezel
Lenguaje:English
Publicado: Sociedad Chilena de Química 2003
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000400004
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spelling oai:scielo:S0717-970720030004000042004-04-26ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPINGdel Valle,M. AngélicaDíaz,Fernando R.Bustos,Fabiola E.Guerra,LiezelConsidering that electropolymerization process occurs via radical intermediates, it was used a stable nitroxide radical such as TEMPO, with the aim to stabilize the species generated in the electrode/solution interface. The obtained results show that TEMPO really acts as a "radical trapping". Therefore, applying an adequate electrochemical perturbation it should be possible the progressive elongation of polymeric chains, and with that, the control over the structure and polydispersity of the depositinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.48 n.4 20032003-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000400004en10.4067/S0717-97072003000400004
institution Scielo Chile
collection Scielo Chile
language English
description Considering that electropolymerization process occurs via radical intermediates, it was used a stable nitroxide radical such as TEMPO, with the aim to stabilize the species generated in the electrode/solution interface. The obtained results show that TEMPO really acts as a "radical trapping". Therefore, applying an adequate electrochemical perturbation it should be possible the progressive elongation of polymeric chains, and with that, the control over the structure and polydispersity of the deposit
author del Valle,M. Angélica
Díaz,Fernando R.
Bustos,Fabiola E.
Guerra,Liezel
spellingShingle del Valle,M. Angélica
Díaz,Fernando R.
Bustos,Fabiola E.
Guerra,Liezel
ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
author_facet del Valle,M. Angélica
Díaz,Fernando R.
Bustos,Fabiola E.
Guerra,Liezel
author_sort del Valle,M. Angélica
title ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
title_short ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
title_full ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
title_fullStr ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
title_full_unstemmed ELECTROPOLYMERIZATION OF CARBAZOLE USING TEMPO AS RADICAL TRAPPING
title_sort electropolymerization of carbazole using tempo as radical trapping
publisher Sociedad Chilena de Química
publishDate 2003
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000400004
work_keys_str_mv AT delvallemangelica electropolymerizationofcarbazoleusingtempoasradicaltrapping
AT diazfernandor electropolymerizationofcarbazoleusingtempoasradicaltrapping
AT bustosfabiolae electropolymerizationofcarbazoleusingtempoasradicaltrapping
AT guerraliezel electropolymerizationofcarbazoleusingtempoasradicaltrapping
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